The synthesis of the given ether by Williamson synthesis methods using any alcohol or phenol. Interpretation: The synthesis of the given ethers by Williamson synthesis using any alcohol and phenol is to be stated. Concept introduction: The reaction of an alkoxide ion with 1 ° alkyl halide through S N 2 mechanism to form ether is known as Williamson synthesis.

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Answer 1

Question

Chapter 14.5, Problem 14.9P

(a)

Interpretation Introduction

To determine: The synthesis of the given ether by Williamson synthesis methods using any alcohol or phenol.

Interpretation: The synthesis of the given ethers by Williamson synthesis using any alcohol and phenol is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(b)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(c)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(d)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(e)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

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Show the combination of alcohol and haloalkane that can best be used to prepare ether by the Williamson ether synthesis.

II. Alcohols in Synthesis B.) How are alcohols used to make ethers in the Williamson ether synthesis? How do you design the synthesis of ethers using both acidic and basic Williamson ether synthesis strategies?

The following series of reactions yields ___________. 1) Butanoic acid and SOCl2; set product aside for use in step 3 2) Bromoethane in excess plus Mg and ether 3) Add the product of step 1 to the reaction mix of step 2 4) When the reaction is complete, add dilute aqueous acid 3-ethylhexan-3-ol 3-ethylheptan-2-ol hexanoic acid hexanal 3-heptanone

Answer 2

Question

Chapter 14.5, Problem 14.9P

(a)

Interpretation Introduction

To determine: The synthesis of the given ether by Williamson synthesis methods using any alcohol or phenol.

Interpretation: The synthesis of the given ethers by Williamson synthesis using any alcohol and phenol is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(b)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(c)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(d)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(e)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

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Answer 3

Question

Chapter 14.5, Problem 14.9P

(a)

Interpretation Introduction

To determine: The synthesis of the given ether by Williamson synthesis methods using any alcohol or phenol.

Interpretation: The synthesis of the given ethers by Williamson synthesis using any alcohol and phenol is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(b)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(c)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(d)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(e)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

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Answer 4

Question

Chapter 14.5, Problem 14.9P

(a)

Interpretation Introduction

To determine: The synthesis of the given ether by Williamson synthesis methods using any alcohol or phenol.

Interpretation: The synthesis of the given ethers by Williamson synthesis using any alcohol and phenol is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(b)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(c)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(d)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(e)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

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Answer 5

Chapter 14.5, Problem 14.9P

(a)

Interpretation Introduction

To determine: The synthesis of the given ether by Williamson synthesis methods using any alcohol or phenol.

Interpretation: The synthesis of the given ethers by Williamson synthesis using any alcohol and phenol is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(b)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(c)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(d)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

(e)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 6

Chapter 14.5, Problem 14.9P

(a)

Interpretation Introduction

To determine: The synthesis of the given ether by Williamson synthesis methods using any alcohol or phenol.

Interpretation: The synthesis of the given ethers by Williamson synthesis using any alcohol and phenol is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 7

Chapter 14.5, Problem 14.9P

(a)

Interpretation Introduction

To determine: The synthesis of the given ether by Williamson synthesis methods using any alcohol or phenol.

Interpretation: The synthesis of the given ethers by Williamson synthesis using any alcohol and phenol is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 8

(b)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 9

(b)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 10

(c)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 11

(c)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 12

(d)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 13

(d)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 14

(e)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 15

(e)

Interpretation Introduction

To determine: The synthesis of the given ethers by Williamson synthesis methods.

Interpretation: The synthesis of the given ethers by Williamson synthesis methods is to be stated.

Concept introduction: The reaction of an alkoxide ion with 1° alkyl halide through SN2 mechanism to form ether is known as Williamson synthesis.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 14.2C - Rank the given solvents in decreasing order of...Ch. 14.2D - Prob. 14.2P Ch. 14.2D - In the presence of 18-crown-6, potassium...Ch. 14.3B - Give a common name (when possible) and a...Ch. 14.3C - Prob. 14.5P Ch. 14.3C - Name the following heterocyclic ethers.Ch. 14.4 - Propose a fragmentation to account for each...Ch. 14.5 - Prob. 14.8P Ch. 14.5 - Prob. 14.9P Ch. 14.6 - Prob. 14.10P

Solution Summary: The author explains that the synthesis of the given ethers by Williamson is to be stated.

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Chapter 14 Solutions