The products for the given transformations are to be predicted. Concept Introduction: Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether. Preparation of Sulphides from Thiols is given below, Mechanism: In the first step, deprotonation of thiol takes place to form thiolate ions. In the second step, thiolate acts as nucleophile and attacks the alkyl halide .

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Answer 1

Question

Chapter 14.11, Problem 23CC

a)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

b)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

c)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

d)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

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Answer 2

Question

Chapter 14.11, Problem 23CC

a)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

b)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

c)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

d)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

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Answer 3

Question

Chapter 14.11, Problem 23CC

a)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

b)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

c)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

d)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

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Answer 4

Question

Chapter 14.11, Problem 23CC

a)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

b)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

c)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

d)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

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Answer 5

Chapter 14.11, Problem 23CC

a)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

b)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

c)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

d)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

Answer 6

Chapter 14.11, Problem 23CC

a)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

Answer 7

Chapter 14.11, Problem 23CC

a)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

Answer 8

b)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

Answer 9

b)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

Answer 10

c)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

Answer 11

c)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

Answer 12

d)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

Answer 13

d)

Interpretation Introduction

Interpretation: The products for the given transformations are to be predicted.

Concept Introduction:

Ether analogs of Sulphur called Sulphide or Thioethers. Common names of these compounds are given by fixing the suffix Sulphide instead of Ether.

Preparation of Sulphides from Thiols is given below,

Mechanism:

In the first step, deprotonation of thiol takes place to form thiolate ions.

In the second step, thiolate acts as nucleophile and attacks the alkyl halide.

Answer 14

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Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 14.2 - Prob. 1LTS Ch. 14.2 - Prob. 1PTS Ch. 14.2 - Prob. 2ATS Ch. 14.2 - Prob. 3ATS Ch. 14.4 - Prob. 4CC Ch. 14.5 - Prob. 2LTS Ch. 14.5 - Prob. 5PTS Ch. 14.5 - Prob. 6ATS Ch. 14.5 - Prob. 7ATS Ch. 14.5 - Prob. 8CC

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