Organic Chemistry - MasteringChemistry
Organic Chemistry - MasteringChemistry
7th Edition
ISBN: 9780321867148
Author: Bruice
Publisher: PEARSON
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Chapter 14.13, Problem 22P

(a)

Interpretation Introduction

Interpretation:

The one that occurs at larger wavenumber has to be identified.

Concept introduction:

IR frequency (cm-1): It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz).

Wavelength: It identified the distance from any point on one wave to the corresponding point on the next wave, or its wavelength is generally measured in nanometers (1 nm=10-9 m).

Stretch vibrations: it is a vibration occurring along the line of the bond a stretching vibration changes the bond length.

Bending vibrations: It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle.

(b)

Interpretation Introduction

Interpretation:

The one which occurs at largest wavenumber has to be identified.

Concept introduction:

IR frequency (cm-1): It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz).

Wavelength: It identified the distance from any point on one wave to the corresponding point on the next wave, or its wavelength is generally measured in nanometers (1 nm=10-9 m).

Stretch vibrations: it is a vibration occurring along the line of the bond a stretching vibration changes the bond length.

Bending vibrations: It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle.

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Students have asked these similar questions
Assuming that the force constants are the same, which occurs at a larger wavenumber: 1. a C - O stretch or a C - Cl stretch? 2. a C - O stretch or a C - C stretch?
Which was likely lost to generate peak A? a.)C b.) CH2 c.) Br d.)Cl
Please interpet this spectrum as far as the major peaks. For example, is the 3438.78 an NH peak or C-O stretch? What about the other main peaks and also the subsitution shown.

Chapter 14 Solutions

Organic Chemistry - MasteringChemistry

Ch. 14.6 - Sketch the mass spectrum expected for...Ch. 14.6 - The mass spectra of 1-methoxybutane,...Ch. 14.6 - Prob. 14PCh. 14.6 - Identify the ketones responsible for the mass...Ch. 14.6 - Prob. 16PCh. 14.6 - Using curved arrows, show the principal fragments...Ch. 14.6 - The reaction of (Z)-2-pentene with water and a...Ch. 14.9 - Prob. 19PCh. 14.9 - Prob. 20PCh. 14.9 - Prob. 21PCh. 14.13 - Prob. 22PCh. 14.14 - Which occur at a larger wavenumber: a. the C O...Ch. 14.14 - Prob. 24PCh. 14.14 - Prob. 25PCh. 14.14 - Rank the following compounds from highest...Ch. 14.14 - Which shows an O H stretch at a larger...Ch. 14.15 - Prob. 28PCh. 14.15 - a. An oxygen-containing compound shows an...Ch. 14.15 - Prob. 30PCh. 14.15 - For each of the following pair of compounds, name...Ch. 14.16 - Which of the following compounds has a vibration...Ch. 14.16 - Prob. 33PCh. 14.17 - A compound with molecular formula C4H6O gives the...Ch. 14.19 - Prob. 35PCh. 14.19 - Prob. 36PCh. 14.20 - Predict the max of the following compound:Ch. 14.20 - Prob. 38PCh. 14.21 - a. At pH = 7 one of the ions shown here is purple...Ch. 14.21 - Prob. 40PCh. 14.22 - Prob. 41PCh. 14.22 - Prob. 42PCh. 14 - In the mass spectrum of the following compounds,...Ch. 14 - Prob. 44PCh. 14 - For each of the following pairs of compounds,...Ch. 14 - Draw structures for a saturated hydrocarbon that...Ch. 14 - a. How could you use IR spectroscopy to determine...Ch. 14 - Assuming that the force constant is approximately...Ch. 14 - In the following boxes, list the types of bonds...Ch. 14 - A mass spectrum shows significant peaks at m/z. =...Ch. 14 - Prob. 51PCh. 14 - Prob. 52PCh. 14 - Prob. 53PCh. 14 - How can you use UV spectroscopy to distinguish...Ch. 14 - Rank the following compounds from highest...Ch. 14 - Rank the following compounds from highest...Ch. 14 - What peaks in their mass spectra can be used to...Ch. 14 - Each of the IR spectra shown below is accompanied...Ch. 14 - Prob. 59PCh. 14 - Prob. 60PCh. 14 - How can IR spectroscopy distinguish between...Ch. 14 - 62. Draw the structure of a carboxylic acid that...Ch. 14 - Prob. 63PCh. 14 - Give approximate wavenumbers for the major...Ch. 14 - Prob. 65PCh. 14 - Prob. 66PCh. 14 - Prob. 67PCh. 14 - The IR spectrum of a compound with molecular...Ch. 14 - Which one of the following live compounds produced...Ch. 14 - Prob. 70PCh. 14 - Phenolphthalein is an acid-base indicator. In...Ch. 14 - Which one of the following five compounds produced...Ch. 14 - The IR and mass spectra for three different...
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