Organic Chemistry
Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
Question
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Chapter 14.6, Problem 11CC

a)

Interpretation Introduction

Interpretation: The products of the following reactions are to be predicted.

Concept Introduction:

The cleavage of ether below acidic conditions results in the formation of two Alkyl halides.

Organic Chemistry, Chapter 14.6, Problem 11CC , additional homework tip  1

The cleavage of Phenyl ether below acidic conditions results in the formation of Phenol and Alkyl halide.

Phenol cannot be further used in the conversion of Halide, because either SN2 or SN1 processes are significant at sp2 hybridized centers.

Hydrogen iodide and Hydrogen bromide are used in the cleavage of Ethers. Hydrogen chloride is less significant and Hydrogen fluoride doesn’t cause acid cleavage of Ethers. The reactivity is a result of relative nucleophilicity of Halide ions.

b)

Interpretation Introduction

Interpretation: The products of the following reactions are to be predicted.

Concept Introduction:

The cleavage of ether below acidic conditions results in the formation of two Alkyl halides.

Organic Chemistry, Chapter 14.6, Problem 11CC , additional homework tip  2

The cleavage of Phenyl ether below acidic conditions results in the formation of Phenol and Alkyl halide.

Phenol cannot be further used in the conversion of Halide, because either SN2 or SN1 processes are significant at sp2 hybridized centers.

Hydrogen iodide and Hydrogen bromide are used in the cleavage of Ethers. Hydrogen chloride is less significant and Hydrogen fluoride doesn’t cause acid cleavage of Ethers. The reactivity is a result of relative nucleophilicity of Halide ions.

c)

Interpretation Introduction

Interpretation: The products of the following reactions are to be predicted.

Concept Introduction:

The cleavage of ether below acidic conditions results in the formation of two Alkyl halides.

Organic Chemistry, Chapter 14.6, Problem 11CC , additional homework tip  3

The cleavage of Phenyl ether below acidic conditions results in the formation of Phenol and Alkyl halide.

Phenol cannot be further used in the conversion of Halide, because either SN2 or SN1 processes are significant at sp2 hybridized centers.

Hydrogen iodide and Hydrogen bromide are used in the cleavage of Ethers. Hydrogen chloride is less significant and Hydrogen fluoride doesn’t cause acid cleavage of Ethers. The reactivity is a result of relative nucleophilicity of Halide ions.

d)

Interpretation Introduction

Interpretation: The products of the following reactions are to be predicted.

Concept Introduction:

The cleavage of ether below acidic conditions results in the formation of two Alkyl halides.

Organic Chemistry, Chapter 14.6, Problem 11CC , additional homework tip  4

The cleavage of Phenyl ether below acidic conditions results in the formation of Phenol and Alkyl halide.

Phenol cannot be further used in the conversion of Halide, because either SN2 or SN1 processes are significant at sp2 hybridized centers.

Hydrogen iodide and Hydrogen bromide are used in the cleavage of Ethers. Hydrogen chloride is less significant and Hydrogen fluoride doesn’t cause acid cleavage of Ethers. The reactivity is a result of relative nucleophilicity of Halide ions.

e)

Interpretation Introduction

Interpretation: The products of the following reactions are to be predicted.

Concept Introduction:

The cleavage of ether below acidic conditions results in the formation of two Alkyl halides.

Organic Chemistry, Chapter 14.6, Problem 11CC , additional homework tip  5

The cleavage of Phenyl ether below acidic conditions results in the formation of Phenol and Alkyl halide.

Phenol cannot be further used in the conversion of Halide, because either SN2 or SN1 processes are significant at sp2 hybridized centers.

Hydrogen iodide and Hydrogen bromide are used in the cleavage of Ethers. Hydrogen chloride is less significant and Hydrogen fluoride doesn’t cause acid cleavage of Ethers. The reactivity is a result of relative nucleophilicity of Halide ions.

f)

Interpretation Introduction

Interpretation: The products of the following reactions are to be predicted.

Concept Introduction:

The cleavage of ether below acidic conditions results in the formation of two Alkyl halides.

Organic Chemistry, Chapter 14.6, Problem 11CC , additional homework tip  6

The cleavage of Phenyl ether below acidic conditions results in the formation of Phenol and Alkyl halide.

Phenol cannot be further used in the conversion of Halide, because either SN2 or SN1 processes are significant at sp2 hybridized centers.

Hydrogen iodide and Hydrogen bromide are used in the cleavage of Ethers. Hydrogen chloride is less significant and Hydrogen fluoride doesn’t cause acid cleavage of Ethers. The reactivity is a result of relative nucleophilicity of Halide ions.

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