ATKINS' PHYSICAL CHEMISTRY
ATKINS' PHYSICAL CHEMISTRY
11th Edition
ISBN: 9780190053956
Author: ATKINS
Publisher: Oxford University Press
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Chapter 15, Problem 15A.1ST

(a)

Interpretation Introduction

Interpretation:

The separation of the {133} planes in an orthorhombic lattice has to be determined.

Concept Introduction:

The separation of planes in an orthorhombic lattice is given by

  1dhkl2=h2a2+k2b2+l2c2

Where,

dhkl= Separation between planes

a, b and c are unit cell parameters.

h, k and l are Miller indices.

(a)

Expert Solution
Check Mark

Answer to Problem 15A.1ST

The separation between the given planes is found out to be 0.19nm.

Explanation of Solution

Given data:

  a=0.82nmb=0.94nmc=0.75nmh=1,k=3andl=3

The separation of planes in an orthorhombic lattice is given by

  1dhkl2=h2a2+k2b2+l2c2

Now,

  1d1332=12(0.82nm)2+32(0.94nm)2+32(0.75nm)2=27.6728nm2d133=0.19nm.

Therefore, the separation between the given planes is found out to be 0.19nm.

(b)

Interpretation Introduction

Interpretation:

The separation of the {399} planes in an orthorhombic lattice has to be determined

Concept Introduction:

The separation of planes in an orthorhombic lattice is given by

  1dhkl2=h2a2+k2b2+l2c2

Where,

dhkl= Separation between planes

a, b and c are unit cell parameters.

h, k and l are Miller indices.

(b)

Expert Solution
Check Mark

Answer to Problem 15A.1ST

The separation between the given planes is found out to be 0.19nm.

Explanation of Solution

Given data:

  a=0.82nmb=0.94nmc=0.75nmh=3,k=9andl=9

The separation of planes in an orthorhombic lattice is given by

  1dhkl2=h2a2+k2b2+l2c2

Now,

  1d3992=32(0.82nm)2+92(0.94nm)2+92(0.75nm)2=249.0552nm2d399=0.063nm.

Therefore, the separation between the given planes is found out to be 0.063nm.

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Chapter 15 Solutions

ATKINS' PHYSICAL CHEMISTRY

Ch. 15 - Prob. 15A.2AECh. 15 - Prob. 15A.2BECh. 15 - Prob. 15A.3AECh. 15 - Prob. 15A.3BECh. 15 - Prob. 15A.4AECh. 15 - Prob. 15A.4BECh. 15 - Prob. 15A.1PCh. 15 - Prob. 15A.2PCh. 15 - Prob. 15A.3PCh. 15 - Prob. 15A.4PCh. 15 - Prob. 15A.5PCh. 15 - Prob. 15A.6PCh. 15 - Prob. 15A.7PCh. 15 - Prob. 15A.8PCh. 15 - Prob. 15A.9PCh. 15 - Prob. 15B.1DQCh. 15 - Prob. 15B.2DQCh. 15 - Prob. 15B.3DQCh. 15 - Prob. 15B.1AECh. 15 - Prob. 15B.1BECh. 15 - Prob. 15B.2AECh. 15 - Prob. 15B.2BECh. 15 - Prob. 15B.3AECh. 15 - Prob. 15B.3BECh. 15 - Prob. 15B.4AECh. 15 - Prob. 15B.4BECh. 15 - Prob. 15B.5AECh. 15 - Prob. 15B.5BECh. 15 - Prob. 15B.6AECh. 15 - Prob. 15B.6BECh. 15 - Prob. 15B.7AECh. 15 - Prob. 15B.7BECh. 15 - Prob. 15B.11AECh. 15 - Prob. 15B.11BECh. 15 - Prob. 15B.12AECh. 15 - Prob. 15B.12BECh. 15 - Prob. 15B.1PCh. 15 - Prob. 15B.2PCh. 15 - Prob. 15B.3PCh. 15 - Prob. 15B.4PCh. 15 - Prob. 15B.6PCh. 15 - Prob. 15B.7PCh. 15 - Prob. 15C.1DQCh. 15 - Prob. 15C.2DQCh. 15 - Prob. 15C.1AECh. 15 - Prob. 15C.2AECh. 15 - Prob. 15C.2BECh. 15 - Prob. 15C.3AECh. 15 - Prob. 15C.3BECh. 15 - Prob. 15C.4AECh. 15 - Prob. 15C.4BECh. 15 - Prob. 15C.5AECh. 15 - Prob. 15C.5BECh. 15 - Prob. 15C.1PCh. 15 - Prob. 15C.2PCh. 15 - Prob. 15C.3PCh. 15 - Prob. 15C.4PCh. 15 - Prob. 15C.5PCh. 15 - Prob. 15C.7PCh. 15 - Prob. 15C.8PCh. 15 - Prob. 15C.9PCh. 15 - Prob. 15D.1DQCh. 15 - Prob. 15D.1AECh. 15 - Prob. 15D.1BECh. 15 - Prob. 15D.2AECh. 15 - Prob. 15D.2BECh. 15 - Prob. 15D.3AECh. 15 - Prob. 15D.3BECh. 15 - Prob. 15D.1PCh. 15 - Prob. 15D.2PCh. 15 - Prob. 15E.1DQCh. 15 - Prob. 15E.1AECh. 15 - Prob. 15E.1BECh. 15 - Prob. 15E.2AECh. 15 - Prob. 15E.2BECh. 15 - Prob. 15E.3AECh. 15 - Prob. 15E.3BECh. 15 - Prob. 15E.5PCh. 15 - Prob. 15F.1DQCh. 15 - Prob. 15F.1AECh. 15 - Prob. 15F.1BECh. 15 - Prob. 15F.2AECh. 15 - Prob. 15F.2BECh. 15 - Prob. 15F.3AECh. 15 - Prob. 15F.3BECh. 15 - Prob. 15F.4AECh. 15 - Prob. 15F.4BECh. 15 - Prob. 15F.5AECh. 15 - Prob. 15F.5BECh. 15 - Prob. 15G.1DQCh. 15 - Prob. 15G.2DQCh. 15 - Prob. 15G.1AECh. 15 - Prob. 15G.1BECh. 15 - Prob. 15.1IA
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