Concept explainers
(a)
Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.
Concept introduction:
1. When the ring is mono-substituted, then there is no need of numbering.
2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.
3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.
4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.
(b)
Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.
Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:
1. When the ring is mono-substituted, then there is no need of numbering.
2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.
3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.
4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.
(c)
Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.
Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:
1. When the ring is mono-substituted, then there is no need of numbering.
2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.
3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.
4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.
(d)
Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.
Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:
1. When the ring is mono-substituted, then there is no need of numbering.
2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.
3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.
4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.
(e)
Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.
Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:
1. When the ring is mono-substituted, then there is no need of numbering.
2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.
3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.
4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.
(f)
Interpretation: The structure corresponding to given IUPAC name of a compound is to be drawn.
Concept introduction: IUPAC nomenclature is a systematic way of naming the organic compounds. The basic principles of IUPAC naming for benzene derivatives are:
1. When the ring is mono-substituted, then there is no need of numbering.
2. When the ring is substituted with same substituents, then numbering to one substituent is given and for other substituent, numbering proceed from clockwise or anticlockwise such that it gets lower number.
3. When the ring is substituted with different substituents, then the numbering is done on the basis of priority.
4. Substituents on benzene ring is also indicated using ortho, meta, para prefix. The prefix ortho is used when substituents are on adjacent carbon, meta is used when substituents are separated by one carbon atom, para is used when substituents are across each other in benzene ring.
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Chapter 15 Solutions
ORGANIC CHEMISTRY W/ALEKS
- Draw the structures for the following compounds.(a) 3-benzyl-4-bromohexane , 4,4-dimethylcyclohexene(b) trans-4,5-dibromohex-2-ene , cis-1,1-dibromo-2-ethyl-2,3-dimethylcyclobutanearrow_forwardDraw the structure that corresponds with each name.(a) 3-ethyloctane (b) 4-isopropyldecane (c) sec-butylcycloheptane(d) 2,3-dimethyl-4-propylnonane (e) 2,2,4,4-tetramethylhexane (f) trans-1,3-diethylcyclopentane(g) cis-1-ethyl-4-methylcyclohexane (h) isobutylcyclopentane (i) tert-butylcyclohexane(j) pentylcyclohexane (k) cyclobutylcyclohexane (l) cis-1-bromo-3-chlorocyclohexanearrow_forwardDraw structures corresponding to the following IUPAC names: (a) p-Bromochlorobenzene (c) m-Chloroaniline (b) p-Bromatolvene (d) 1-Chloro-3,5-dimethylbenzenearrow_forward
- Draw a structure for each compound (includes old and new names).(a) 3-methylpent-1-ene (b) cis-3-methyl-3-hexene (c) 3,4-dibromobut-1-ene(d) 1,3-cyclohexadienearrow_forward3) Give the IUPAC names for the following structures: (a) NH2 NO2 (c) (d) C-H NH2 Br H3Carrow_forwardDraw structures corresponding to the following IUPAC names: (a) 2-Methyl-1,5-hexadiene (b) 3-Ethyl-2,2-dimethyl-3-heptene (c) 2,3,3-Trimethyl-1,4,6-octatriene (d) 3,4-Diisopropyl-2,5-dimethyl-3-hexenearrow_forward
- Draw structural formulas for the following the compounds: (a) Cis-1,3-diphenylcyclohexane (b) 5-phenylpentanoic acid (c) 3,4-dibromo-N,N-dimethylanilinearrow_forward25. What is the systematic name for a compound with the following structure? CH2-Br CH3-CH2-CH-CH3 (A) 2-bromoisopentane (B) 1-bromo-2-methylbutane (C) 2-(bromomethyl)butane (D) 2-bromo-2-methylbutanearrow_forwardH,C-CH-CH-CH, CHO (a) 3-ethyl-2-methybutanal (b) 2, 3-dimethylpentanal (c) 2-ethyl-3-methylbutanal (d) 2-ethyl-3-methylbutan-3-al CHO 2. The IUPAC name of is Br (a) 2-methyl-3-bromohexanal (b) 3-bromo-2-methylbutanal (c) 2-methyl-3-bromobutanal (d) 3-bromo-2-methylpentanal 3. The IUPAC name of the compound HO- isarrow_forward
- Draw structures (these may be either skeletal or displayed formulae) for the followingmolecules: (a) 2-methylbutanal(b) 1,6-diaminohexane(c) 1,1,2-trichloroethane(d) 2-methylcyclopentanone(e) but-2-ene-1-olarrow_forward34) The product formed by the reaction of toluene with chlorine in the presence of sunlight is: (a) o-chlorotoluene (b) 2,4-dichlorotoluene (c) p-chlorotoluene (d) Benzylchloridearrow_forwardPlease draw: (a) trans-2,3-dibromo-2-hexene (b) 1-ethyl-3-methylcyclohexane (c) 4-isopropyl-3-octanolarrow_forward
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