Given that the substitution reaction of toluene with Br 2 can, in principle, lead to the formation of three isomeric bromotoluene products. In practice, however, only o- and p-bromotoluene are formed in substantial amounts. The meta isomer is not formed. The structures of three possible carbocation intermediates are to be drawn and the predominance of ortho and para products over the meta product is to be explained. Concept introduction: When a monosubstituted benzene is subjected to electrophilic substitution reaction, the electrophile in principle can get substituted in any of the three positions, ortho, meta and para. Which isomer will be formed predominantly depends on the stability of the allylic intermediate formed by the attack of the electrophile on the benzene ring. The more stable intermediate will yield the products. To draw: The structures of three possible carbocation intermediates formed during the substitution reaction of toluene that leads to the formation of o-, p- and m-bromotoluenes. To explain: The observation when toluene reacts with bromine the ortho and para products are formed predominantly than the meta product.

Question

CCH H20, H2SO4 H9SO4 CH3 Alkynes do not react directly with aqueous acid as do alkenes, but will do so in the presence of mercury(II) sulfate as a Lewis acid catalyst. The reaction occurs with Markovnikov regiochemistry, so the OH group adds to the more highly substituted carbon and the H adds to the less highly substituted carbon. The initial product of the reaction is a vinyl alcohol, also called an enol. The enol immediately rearranges to a more stable ketone via tautomerization. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions Hjö: -CH3 -CH3 H3O*

Answer 1

Question

Chapter 15.SE, Problem 52AP

Interpretation Introduction

Interpretation:

Given that the substitution reaction of toluene with Br₂ can, in principle, lead to the formation of three isomeric bromotoluene products. In practice, however, only o- and p-bromotoluene are formed in substantial amounts. The meta isomer is not formed. The structures of three possible carbocation intermediates are to be drawn and the predominance of ortho and para products over the meta product is to be explained.

Concept introduction:

When a monosubstituted benzene is subjected to electrophilic substitution reaction, the electrophile in principle can get substituted in any of the three positions, ortho, meta and para. Which isomer will be formed predominantly depends on the stability of the allylic intermediate formed by the attack of the electrophile on the benzene ring. The more stable intermediate will yield the products.

To draw:

The structures of three possible carbocation intermediates formed during the substitution reaction of toluene that leads to the formation of o-, p- and m-bromotoluenes.

To explain:

The observation when toluene reacts with bromine the ortho and para products are formed predominantly than the meta product.

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