(a) Interpretation: The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated. Concept introduction: The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

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Answer 1

Question

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

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Students have asked these similar questions

Nucleophilic aromatic substitution provides one of the common methods for making phenols. Show how you would synthesize the following phenols, using benzene or toluene as your aromatic starting material, and explain why mixtures of products would be obtained in some cases.(a) p-nitrophenol (b) 2,4,6-tribromophenol (c) p-chlorophenol

Electrophilic aromatic substitution usually occurs at the 1-position of naphthalene, also called the a position. Predict the major products of the reactions of naphthalene with the following reagents.(a) isobutylene and HF (b) cyclohexanol and BF3 (c) fuming sulfuric acid

(a) The Friedel-Crafts reaction of benzene with 2-chloro-3-methylbutane in the presence of AlCl3 occurs with a carbocation rearrangement. Give mechanistic explanation and the product formed. (b) Predict the product(s) will be formed from the following reactions: (i) Bromination of p-methylbenzoic acid (ii) Sulphonation of m-bromoanisole (iii) Friedel-craft acylation of o-bromonitrobenzene

Answer 2

Question

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

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Answer 3

Question

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

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Answer 4

Question

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

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Answer 5

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

Answer 6

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Answer 7

Chapter 16, Problem 16.31P

Interpretation Introduction

(a)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction is to be stated.

Concept introduction:

The organic reaction of an arene in which the replacement of a hydrogen atom by a sulfonic acid takes place is known as aromatic sulfonation. This reaction is an aromatic substitution reaction. The substitution in sulfonation reaction is reversible.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The ranking of the compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the Friedel-Crafts acylation is to be stated.

Concept introduction:

The reaction between isobutyryl chloride with benzene in presence of AlCl3 is a Friedal Craft acylation reaction. In this, AlCl3 acts as a Lewis acid catalyst. It is a method of insertion of carbonyl group on benzene ring.

Answer 10

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Answer 12

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Answer 13

Ch. 16 - Prob. 16.1P Ch. 16 - Prob. 16.2P Ch. 16 - Prob. 16.3P Ch. 16 - Prob. 16.4P Ch. 16 - Prob. 16.5P Ch. 16 - Prob. 16.6P Ch. 16 - Prob. 16.7P Ch. 16 - Prob. 16.8P Ch. 16 - Prob. 16.9P Ch. 16 - Prob. 16.10P

Solution Summary: The author analyzes the ranking of compounds in increasing order of their harshness of the reaction conditions that are required to accomplish the sulfonation reaction.

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