Chemistry: Atoms First
18th Edition
ISBN: 9781938168154
Author: Richard Langley, Klaus Theopold, Paul Flowers
Publisher: OpenStax College
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Textbook Question
Chapter 16, Problem 28E
For each pair of standard free energy change and electron stoichiometry values below, calculate a corresponding standard cell potential.
(a)
(b)
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Chemistry: Atoms First
Ch. 16 - Identify each half-reaction below as either...Ch. 16 - Identify each half-reaction below as either...Ch. 16 - Assuming each pair of half-reactions below takes...Ch. 16 - Balance the equations below assuming they occur in...Ch. 16 - Identify the oxidant and reductant of each...Ch. 16 - Balance the equations below assuming they occur in...Ch. 16 - Identify the oxidant and reductant of each...Ch. 16 - Why dont hydroxide ions appear in equations for...Ch. 16 - Why dont hydrogen ions appear in equations for...Ch. 16 - Why must the charge balance in oxidation-reduction...
Ch. 16 - Write cell schematics for the following cell...Ch. 16 - Assuming the schematics below represent galvanic...Ch. 16 - Write a balanced equation for the cell reaction of...Ch. 16 - Balance each reaction below, and write a cell...Ch. 16 - Identify the oxidant and reductant in each...Ch. 16 - From the information provided, use cell notation...Ch. 16 - Why is a salt bridge necessary in galvanic cell...Ch. 16 - An active (metal) electrode was found to gain mass...Ch. 16 - An active (metal) electrode was found to lose mass...Ch. 16 - The masses of three electrodes (A, B, and C), each...Ch. 16 - Calculate the standard cell potential for each...Ch. 16 - Calculate the standard cell potential for each...Ch. 16 - Write the balanced cell reaction for the cell...Ch. 16 - Determine the cell reaction and standard cell...Ch. 16 - Determine the cell reaction and standard cell...Ch. 16 - Write the balanced cell reaction for the cell...Ch. 16 - For each pair of standard cell potential and...Ch. 16 - For each pair of standard free energy change and...Ch. 16 - Determine the standard cell potential and the cell...Ch. 16 - Determine ∆G and ∆G for each of the reactions...Ch. 16 - Use the data in Appendix L to calculate...Ch. 16 - Consider a battery made from one half-cell that...Ch. 16 - Consider a battery with the overall reaction:...Ch. 16 - Why do batteries go dead, but fuel cells do not?Ch. 16 - Use the Nernst equation to explain the drop in...Ch. 16 - Using the information thus far in this chapter,...Ch. 16 - Which member of each pair of metals is more likely...Ch. 16 - Consider the following metals: Ag, Au, Mg, Ni, and...Ch. 16 - Aluminum (EoA13+/A1=-2.07V) is easily oxidized...Ch. 16 - If a sample of iron and a sample of zinc come into...Ch. 16 - Suppose you have three different metals. A, B, and...Ch. 16 - Why would a sacrificial anode made of lithium...Ch. 16 - If a 2.5 A current flows through a circuit for 35...Ch. 16 - For the scenario in the previous question, how...Ch. 16 - Write the half-reactions and cell reaction...Ch. 16 - What mass of each product is produced in each of...Ch. 16 - How long would it take to reduce 1 mole of each of...Ch. 16 - A Current of 2.345 A passes through the Shown in...Ch. 16 - An irregularly shaped metal part made from a...
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- Calculate the standard cell potential of the following cell at 25C. Sn(s)Sn2+(aq)I2(aq)I(aq)arrow_forwardWhat is the standard cell potential you would obtain from a cell at 25C using an electrode in which Hg22+(aq) is in contact with mercury metal and an electrode in which an aluminum strip dips into a solution of Al3+(aq)?arrow_forwardFor each reaction listed, determine its standard cell potential at 25 C and whether the reaction is spontaneous at standard conditions. (a) Mn(s)+Ni2+(aq)Mn2+(aq)+Ni(s) (b) 3Cu2+(aq)+2Al(s)2Al3+(aq)+3Cu(s) (c) Na(s)+LiNO3(aq)NaNO3(aq)+Li(s) (d) Ca(NO3)2(aq)+Ba(s)Ba(NO3)2(aq)+Ca(s)arrow_forward
- Calculate the standard cell potential of the cell corresponding to the oxidation of oxalic acid, H2C2O4, by permanganate ion. MnO4. 5H2C2O4(aq)+2MnO4(aq)+6H+(aq)10CO2(g)+2Mn2+(aq)+8H2O(l) See Appendix C for free energies of formation: Gf for H2C2O4(aq) is 698 kJ.arrow_forwardFor each of the reactions, calculate E from the table of standard potentials, and state whether the reaction is spontaneous as written or spontaneous in the reverse direction under standard conditions. (a) Zn(s)+Fe2+(aq)Zn2+(aq)+Fe(s) (b) AgCl(s)+Fe2+(aq)Ag(s)+Fe3+(aq)+Cl(aq) (c) Br2(l)+2Cl(aq)Cl2(g)+2Br(aq)arrow_forwardAn electrode is prepared from liquid mercury in contact with a saturated solution of mercury(I) chloride, Hg2Cl, containing 1.00 M Cl . The cell potential of the voltaic cell constructed by connecting this electrode as the cathode to the standard hydrogen half-cell as the anode is 0.268 V. What is the solubility product of mercury(I) chloride?arrow_forward
- Calcium metal can be obtained by the direct electrolysis of molten CaCl2, at a voltage of 3.2 V. (a) How many joules of electrical energy are required to obtain 12.0 1b of calcium? (b) What is the cost of the electrical energy obtained in (a) if electrical energy is sold at the rate of nine cents per kilowatt hour?arrow_forwardFor each of the following reactions, determine the overall balanced electrochemical reaction, its standard electric potential, and the standard Gibbs energy of the reaction. aCo+F2Co2++2F bZn+Fe2+Zn2++Fe c Zn+Fe3+Zn2++Fe d Hg2++HgHg22+arrow_forwardConsider the following cell reaction at 25C. 2Cr(s)+3Fe2+(aq)2Cr3+(aq)+3Fe(s) Calculate the standard cell potential of this cell from the standard electrode potentials, and from this obtain G for the cell reaction. Use data in Appendix C to calculate H; note that Cr(H2O)63+(aq) equals Cr3+(aq). Use these values of H and G to obtain S for the cell reaction.arrow_forward
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