The reaction sequence for each of the given conversion required two synthetic steps with suitable reagents is to be suggested. Concept introduction: The ketone on reduction with sodium borohydride gives secondary alcohols. The alcohol on dehydration in presence of acid catalyst eliminates water molecule and forms double bond. The primary alcohols on oxidation with good oxidizing agent forms carboxylic acid. The tertiary alcohol does not undergo oxidation to form carbonyl compound. Vicinal diols on treatment with periodic acid ( HIO 4 ) undergoes cleavage of carbon-carbon bond of vicinal diol and results in two carbonyl compounds. The dihydroxylation is the addition of two hydroxyl groups to the double bond of alkene to form a 1,2 diol. The both hydroxyl groups add to double bond from same side of double bond.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 16, Problem 29P

Interpretation Introduction

Interpretation:

The reaction sequence for each of the given conversion required two synthetic steps with suitable reagents is to be suggested.

Concept introduction:

The ketone on reduction with sodium borohydride gives secondary alcohols.

The alcohol on dehydration in presence of acid catalyst eliminates water molecule and forms double bond.

The primary alcohols on oxidation with good oxidizing agent forms carboxylic acid.

The tertiary alcohol does not undergo oxidation to form carbonyl compound.

Vicinal diols on treatment with periodic acid (HIO4) undergoes cleavage of carbon-carbon bond of vicinal diol and results in two carbonyl compounds.

The dihydroxylation is the addition of two hydroxyl groups to the double bond of alkene to form a 1,2 diol. The both hydroxyl groups add to double bond from same side of double bond.

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Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 16, Problem 29P

Interpretation Introduction

Interpretation:

The reaction sequence for each of the given conversion required two synthetic steps with suitable reagents is to be suggested.

Concept introduction:

The ketone on reduction with sodium borohydride gives secondary alcohols.

The alcohol on dehydration in presence of acid catalyst eliminates water molecule and forms double bond.

The primary alcohols on oxidation with good oxidizing agent forms carboxylic acid.

The tertiary alcohol does not undergo oxidation to form carbonyl compound.

Vicinal diols on treatment with periodic acid (HIO4) undergoes cleavage of carbon-carbon bond of vicinal diol and results in two carbonyl compounds.

The dihydroxylation is the addition of two hydroxyl groups to the double bond of alkene to form a 1,2 diol. The both hydroxyl groups add to double bond from same side of double bond.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 16, Problem 29P

Interpretation Introduction

Interpretation:

The reaction sequence for each of the given conversion required two synthetic steps with suitable reagents is to be suggested.

Concept introduction:

The ketone on reduction with sodium borohydride gives secondary alcohols.

The alcohol on dehydration in presence of acid catalyst eliminates water molecule and forms double bond.

The primary alcohols on oxidation with good oxidizing agent forms carboxylic acid.

The tertiary alcohol does not undergo oxidation to form carbonyl compound.

Vicinal diols on treatment with periodic acid (HIO4) undergoes cleavage of carbon-carbon bond of vicinal diol and results in two carbonyl compounds.

The dihydroxylation is the addition of two hydroxyl groups to the double bond of alkene to form a 1,2 diol. The both hydroxyl groups add to double bond from same side of double bond.

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Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 16, Problem 29P

Interpretation Introduction