Organic Chemistry - Standalone book
Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 16.2, Problem 2P
Interpretation Introduction

Interpretation:

The structural formulae of the products of the given reactions that reflect the position of the deuterium atom in each of the product are to be determined.

Concept introduction:

The sodium borohydride (NaBH4) and lithium aluminum hydride (LiAlH4) act as a hydrogen donor compound.

The sodium borohydride (NaBH4) reduces the aldehydes and ketones to corresponding alcohols and the hydrogen atom that is bonded to carbonyl compound comes from borohydride.

The lithium aluminum hydride (LiAlH4) reduces almost all types of carbonyl compounds to their corresponding alcohols the hydrogen atom that is bonded to carbonyl compound comes from aluminum hydride

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1. There are five constitutional isomers with the molecular formula C6H14. When treated with chlorine at 300°C, isomer A gives a mixture of two monochlorination products. Under the same conditions, isomer B gives a mixture of five monochlorination products, isomer C gives four monochlorination products, and isomer D gives a mixture of three monochlorination products. From this information, draw the structure of isomer B.   2. Is it possible to prepare 1-chloro-2,2-dimethylpropane in high yield by halogenation of an alkane? _____no/yes   How many monohalo isomers are possible upon radical halogenation of the parent alkane? _____   (Consider stereoisomers as well.) Please answer very soon will give rating surely Both questions answers needed
5. How many isomers are there Of C6H14? 6. Aside from a halogenated alkane, what other product results from the bromination of hexane? Write the formula
A compound with formula C7H12O is treated with sodium borohydride in methanol to yield 2,2-dimethylcylopentanol. Write a reaction scheme showing the structures of the reactant, the reagents, and the product. Will the product be optically active? Explain.

Chapter 16 Solutions

Organic Chemistry - Standalone book

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