Concept explainers
The following reaction occurs at the cathode of an
Which anode reaction would produce a battery with the highest voltage?
a.
b.
c.
d.
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Introductory Chemistry, Books a la Carte Edition (5th Edition)
- Consider a galvanic cell based on the following half-reactions: a. What is the expected cell potential with all components in their standard states? b. What is the oxidizing agent in the overall cell reaction? c. What substances make up the anode compartment? d. In the standard cell, in which direction do the electrons flow? e. How many electrons are transferred per unit of cell reaction? f. If this cell is set up at 25C with [Fe2+] = 2.00 104 M and [La3+] = 3.00 103 M, what is the expected cell potential?arrow_forwardA voltaic cell is constructed in which one half-cell consists of a silver wire in an aqueous solution of AgNO3.The other half cell consists of an inert platinum wire in an aqueous solution containing Fe2+(aq) and Fe3+(aq). (a) Calculate the cell potential, assuming standard conditions. (b) Write the net ionic equation for the reaction occurring in the cell. (c) Which electrode is the anode and which is the cathode? (d) If [Ag+] is 0.10 M, and [Fe2+] and [Fe3+] are both 1.0 M, what is the cell potential? Is the net cell reaction still that used in part (a)? If not, what is the net reaction under the new conditions?arrow_forwardFor the reaction Cu2+(aq) + Zn(s) → Cu(s) + Zn2+ (aq), why can’t you generate electric current by placing a piece of copper metal and a piece of zinc metal in a solution containing CuCl2(aq) and ZnCl2(aq)?arrow_forward
- You have 1.0 M solutions of Al(NO3)3 and AgNO3 along with Al and Ag electrodes to construct a voltaic cell. The salt bridge contains a saturated solution of KCl. Complete the picture associated with this problem by a writing the symbols of the elements and ions in the appropriate areas (both solutions and electrodes). b identifying the anode and cathode. c indicating the direction of electron flow through the external circuit. d indicating the cell potential (assume standard conditions, with no current flowing). e writing the appropriate half-reaction under each of the containers. f indicating the direction of ion flow in the salt bridge. g identifying the species undergoing oxidation and reduction. h writing the balanced overall reaction for the cell.arrow_forwardAn aqueous solution of an unknown salt of gold is electrolyzed by a current of 2.75 amps for 3.39 hours. The electroplating is carried out with an efficiency of 93.0%, resulting in a deposit of 21.221 g of gold. a How many faradays are required to deposit the gold? b What is the charge on the gold ions (based on your calculations)?arrow_forwardA potential of 0.142 V is recorded (under standard conditions) for a voltaic cell constructed using the following half reactions: Cathode: Pb2+(aq) + 2 e Pb(s) Anode: PbCl2(s) + 2 e Pb(s) + 2 Cl(aq) Net: Pb2+(aq) + 2 Cl(aq) PbCI2(s) (a) What is the standard reduction potential for the anode reaction? (b) Calculate the solubility product, Ksp, for PbCl2.arrow_forward
- Draw a diagram of each cell. Label the anode, the cathode, the species in each half-cell solution, the direction of electron movement in an external circuit, and thedirection of movement of ions within the cell. (a) Cu(s) | Cu2+(aq) || Fe2+(aq) |Fe(s) (b) Pt(s) | H2O2(aq), H+(aq) || Fe2+(aq), Fe3+(aq) | Pt(s)arrow_forwardA voltaic cell is constructed using the reaction of chromium metal and iron(II) ions. 2 Cr(s) + 3 Fe2+(aq) 2 Cr3+(aq) + 3 Fe(s) Complete the following sentences: Electrons in the external circuit flow from the ________ electrode to the ______ electrode. Negative ions move in the salt bridge from the ________ half-cell to the ______ half-cell. The half-reaction at the anode is _______ and that at the cathode is ________.arrow_forwardConsider the cell Pt|H2|H+H+|H2|Pt In the anode half-cell, hydrogen gas at 1.0 atm is bubbled over a platinum electrode dipping into a solution that has a pH of 7.0. The other half-cell is identical to the first except that the solution around the platinum electrode has a pH of 0.0. What is the cell voltage?arrow_forward
- Use Table 17.1 to arrange the following oxidizing agents in order of increasing strength: Mn2+ S Co3+ Cl2 K+arrow_forwardFour voltaic cells are set up. In each, one half-cell contains a standard hydrogen electrode. The second half-cell is one of the following: (i) Cr3+(aq, 1.0 M)|Cr(s) (ii) Fea+(aq, 1.0M)|Fe(s) (iii) Cu2+(aq, 1.0M)|Cu(s) (iv) Mg2+(aq, 1.0M)|Mg(s) (a) In which of the voltaic cells does the hydrogen electrode serve as the cathode? (b) Which voltaic cell produces the highest potential? Which produces the lowest potential?arrow_forward
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