the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

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Answer 1

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Chapter 16, Problem 97P

(a)

Interpretation Introduction

Interpretation:

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

(b)

Interpretation Introduction

Interpretation:

The rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in acidic solution has to be determined.

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When the rate constants for the hydrolysis of several morpholine enamines of para-substituted propiophenones are determined at pH 4.7, the r value is positive; however, when the rates of hydrolysis are determined at pH 10.4, the r value is negative. a. What is the rate-determining step of the hydrolysis reaction when it is carried out in a basic solution? b. What is the rate-determining step of the hydrolysis reaction when it is carried out in an acidic solution?

The hydrolysis of the ester shown here is catalyzed by morpholine. Explain how morpholine catalyzes the reaction. (Hint: The pKa of the conjugateacid of morpholine is 9.3, so morpholine is too weak a base to function as a base catalyst.)

One of the heptanedione isomers below has a pka of approximately 9 rather than 20. Which isomer? Why? Draw its conjugate base and offer a full explanation of its acidity.

Answer 2

Question

Chapter 16, Problem 97P

(a)

Interpretation Introduction

Interpretation:

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

(b)

Interpretation Introduction

Interpretation:

The rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in acidic solution has to be determined.

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Answer 3

Question

Chapter 16, Problem 97P

(a)

Interpretation Introduction

Interpretation:

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

(b)

Interpretation Introduction

Interpretation:

The rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in acidic solution has to be determined.

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Answer 4

Question

Chapter 16, Problem 97P

(a)

Interpretation Introduction

Interpretation:

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

(b)

Interpretation Introduction

Interpretation:

The rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in acidic solution has to be determined.

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Answer 5

Chapter 16, Problem 97P

(a)

Interpretation Introduction

Interpretation:

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

(b)

Interpretation Introduction

Interpretation:

The rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in acidic solution has to be determined.

Answer 6

Chapter 16, Problem 97P

(a)

Interpretation Introduction

Interpretation:

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

Answer 7

Chapter 16, Problem 97P

(a)

Interpretation Introduction

Interpretation:

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in acidic solution has to be determined.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in acidic solution has to be determined.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 16.1 - Give two names for each of the following:Ch. 16.1 - Prob. 2P Ch. 16.1 - Name the following:Ch. 16.2 - Prob. 4P Ch. 16.4 - What products are formed when the following...Ch. 16.4 - We saw on the previous page that...Ch. 16.4 - a. How many stereoisomers are obtained from the...Ch. 16.4 - Prob. 9P Ch. 16.4 - Write the mechanism for the reaction of acetyl...Ch. 16.4 - Prob. 11P

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

Solution Summary: The author describes the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

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Interpretation:

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

Interpretation:

The rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in acidic solution has to be determined.

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Chapter 16 Solutions

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

Solution Summary: The author describes the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

Concept explainers

Videos

Interpretation: the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

Interpretation: The rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in acidic solution has to be determined.

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Chapter 16 Solutions

Interpretation:

the rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in basic solution has to be determined.

Interpretation:

The rate determining step of hydrolysis reaction of morpholine enamines of para-substituted propiophenones when the reaction carried out in acidic solution has to be determined.