(a)
Interpretation: The acid chloride which is needed to prepare the given
Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction.
(b)
Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.
Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction.
(c)
Interpretation: The acid chloride which is needed to prepare the given ketones from benzene using a Friedel-Craft acylation is to be predicted.
Concept introduction: The Friedel-Craft acylation is a type of electrophilic substitution reaction.
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Chapter 16 Solutions
EBK ORGANIC CHEMISTRY
- What is the major organic product obtained from the following reaction? A. B. CI لله مللی حمله C. D. فيarrow_forwardUsing ethynylcyclohexane as a starting material and any other needed reagents, how can the following compounds be synthesized?arrow_forwardWhat hydrolysis products are formed when the following compound is treated with aqueous acid?arrow_forward
- Esters and amides are most easily made by nucleophilic acyl substitution reactions on… A. alcohols B. acid chlorides C. acid anhydrides D. carboxylates E. carboxylic acidsarrow_forwardWhich of the foll owing lone pairs of purine participate in its aromaticity? A N. N.B N. Carrow_forwardDraw the structure of both an acid chloride and an ester that can be used to prepare each compound by reduction.arrow_forward
- What product is formed when A is treated with Grubbs catalyst underhigh-dilution conditions? This reaction was a key step in the synthesis ofstemoamide, the naturally occurring amide described in the opening paragraph.arrow_forwardWhat carbonyl compound and amine or alcohol are needed to prepare each product?arrow_forwardThe following product was obtained from the ozonolysis of an alkene followed by treatment with dimethyl sulfide. What is the structure of the alkene?arrow_forward
- 2. How many different ß-hydroxyaldehydes and ß-hydroxyketones, including constitutional isomers and stereoisomers, are formed upon treatment of a mixture of acetone and benzaldehyde with base? a. b. 2 c. 3 d. 4arrow_forward2. Name and Draw the structures of all possible chemical (Electrophilic aromatic substitution) reactions of the phenol compound namely; A.Friedal Craft Alkylation B.Friedal Craft Acylationarrow_forwardWhat is the product formed when each dicarbonyl compound undergoes an intramolecular aldol reaction, followed by dehydration.arrow_forward
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning