Concept explainers
(a)
Interpretation:
The given set of compounds has to be arranged in the increasing order of boing point.
Concept introduction:
The boiling points of carboxylic acids are higher than those of alcohol or
Intermolecular hydrogen bonding will increase the boiling point of an organic compound.
Carboxylic acids can form dimers in which hydrogen bonds form between two carboxyl groups this will also increase their boiling point.
Increasing order of boiling point of some organic compounds with similar molecular weight is shown below,
The better hydrogen bond capability of a molecule will increase its boiling points.
(b)
Interpretation:
The given set of compounds has to be arranged in the increasing order of boing point.
Concept introduction:
The boiling points of carboxylic acids are higher than those of alcohol or aldehydes of similar relative molecular mass due to intermolecular hydrogen bonding.
Carboxylic acids can form dimers in which hydrogen bonds form between two carboxyl groups this will also increase their boiling point.
Intermolecular hydrogen bonding will increase the boiling point of an organic compound.
Increasing order of boiling point of some organic compounds with similar molecular weight is shown below,
The better hydrogen bond capability of a molecule will increase its boiling points.
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Chapter 17 Solutions
OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition
- Arrange these compounds in order of increasing boiling point (values in C are 42, 24, 78, and 118). (a) CH3CH2OH (b) CH3OCH3 (c) CH3CH2CH3 (d) CH3COOHarrow_forwardWhat is the IUPAC name for the following compound? CH₂CH₂OH CH3CH₂C=CCH₂CH3 CH3 (A) 3-methyl-4-ethyl-3-hexen-6-ol B 4-ethyl-3-methyl-3,6-hexenol 3-ethyl-4-methyl-3-hexen-1-ol 3-methyl-4-(2-hydroxyethyl)-3-hexene E 3-(2-hydroxyethyl)-3-methyl-3-hexenearrow_forwardArrange the alkenes in each set in order of increasing rate of reaction with HI and explain the basis for your ranking. Draw the structural formula of the major product formed in each case. (a) and (b) H3CH₂CHC=CH₂ and (H3C) 2C=CHCH3arrow_forward
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- 6) Draw the product of the reaction of ethanol with each of the following. a CH₂C=C b (CH3)3N:arrow_forwardGive a common name (when possible) and a systematic name for each compound. ) (h) CH3C‚CCH2OCH3arrow_forwardProvide the IUPAC name for each of the following compounds. Pay attention to stereochemistry. (c) (a) (Б) О NO2 OH NH2 ОН NH2arrow_forward
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- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning