The structure of methyl formate, formamide and formic acid has to be drawn and hydrogen bonding formed between molecules of each kind has to be indicated using dashed lines. Concept Introduction: Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom in the molecules.

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Answer 1

Question

Chapter 17, Problem 17.35UKC

(a)

Interpretation Introduction

Interpretation:

The structure of methyl formate, formamide and formic acid has to be drawn and hydrogen bonding formed between molecules of each kind has to be indicated using dashed lines.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom in the molecules.

(b)

Interpretation Introduction

Interpretation:

The compounds have to be arranged in the increasing order of boiling point and the reason for the different boiling points has to be explained.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom in the molecules.

The boiling points of aliphatic amines are higher than those of alkanes or halo alkanes of similar relative molecular mass due to intermolecular hydrogen bonding.

The N-H bond is more polar than the C-H bond but less polar than O-H bond.

Increasing order of boiling point of some organic compounds with similar molecular weight can be represented as follows,

Alkane < Ether < Alkyl halide < Amine < Ketone , aldehyde < Alcohol < Carboxylic acid

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Answer 2

Question

Chapter 17, Problem 17.35UKC

(a)

Interpretation Introduction

Interpretation:

The structure of methyl formate, formamide and formic acid has to be drawn and hydrogen bonding formed between molecules of each kind has to be indicated using dashed lines.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom in the molecules.

(b)

Interpretation Introduction

Interpretation:

The compounds have to be arranged in the increasing order of boiling point and the reason for the different boiling points has to be explained.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom in the molecules.

The boiling points of aliphatic amines are higher than those of alkanes or halo alkanes of similar relative molecular mass due to intermolecular hydrogen bonding.

The N-H bond is more polar than the C-H bond but less polar than O-H bond.

Increasing order of boiling point of some organic compounds with similar molecular weight can be represented as follows,

Alkane < Ether < Alkyl halide < Amine < Ketone , aldehyde < Alcohol < Carboxylic acid

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Answer 3

Question

Chapter 17, Problem 17.35UKC

(a)

Interpretation Introduction

Interpretation:

The structure of methyl formate, formamide and formic acid has to be drawn and hydrogen bonding formed between molecules of each kind has to be indicated using dashed lines.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom in the molecules.

(b)

Interpretation Introduction

Interpretation:

The compounds have to be arranged in the increasing order of boiling point and the reason for the different boiling points has to be explained.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom in the molecules.

The boiling points of aliphatic amines are higher than those of alkanes or halo alkanes of similar relative molecular mass due to intermolecular hydrogen bonding.

The N-H bond is more polar than the C-H bond but less polar than O-H bond.

Increasing order of boiling point of some organic compounds with similar molecular weight can be represented as follows,

Alkane < Ether < Alkyl halide < Amine < Ketone , aldehyde < Alcohol < Carboxylic acid

Expert Solution & Answer

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Answer 4

Question

Chapter 17, Problem 17.35UKC

(a)

Interpretation Introduction

Interpretation:

The structure of methyl formate, formamide and formic acid has to be drawn and hydrogen bonding formed between molecules of each kind has to be indicated using dashed lines.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom in the molecules.

(b)

Interpretation Introduction

Interpretation:

The compounds have to be arranged in the increasing order of boiling point and the reason for the different boiling points has to be explained.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom in the molecules.

The boiling points of aliphatic amines are higher than those of alkanes or halo alkanes of similar relative molecular mass due to intermolecular hydrogen bonding.

The N-H bond is more polar than the C-H bond but less polar than O-H bond.

Increasing order of boiling point of some organic compounds with similar molecular weight can be represented as follows,

Alkane < Ether < Alkyl halide < Amine < Ketone , aldehyde < Alcohol < Carboxylic acid

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Answer 5

Chapter 17, Problem 17.35UKC

(a)

Interpretation Introduction

Interpretation:

The structure of methyl formate, formamide and formic acid has to be drawn and hydrogen bonding formed between molecules of each kind has to be indicated using dashed lines.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom in the molecules.

(b)

Interpretation Introduction

Interpretation:

The compounds have to be arranged in the increasing order of boiling point and the reason for the different boiling points has to be explained.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom in the molecules.

The boiling points of aliphatic amines are higher than those of alkanes or halo alkanes of similar relative molecular mass due to intermolecular hydrogen bonding.

The N-H bond is more polar than the C-H bond but less polar than O-H bond.

Increasing order of boiling point of some organic compounds with similar molecular weight can be represented as follows,

Alkane < Ether < Alkyl halide < Amine < Ketone , aldehyde < Alcohol < Carboxylic acid

Answer 6

Chapter 17, Problem 17.35UKC

(a)

Interpretation Introduction

Interpretation:

The structure of methyl formate, formamide and formic acid has to be drawn and hydrogen bonding formed between molecules of each kind has to be indicated using dashed lines.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom in the molecules.

Answer 7

Chapter 17, Problem 17.35UKC

(a)

Interpretation Introduction

Interpretation:

The structure of methyl formate, formamide and formic acid has to be drawn and hydrogen bonding formed between molecules of each kind has to be indicated using dashed lines.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom in the molecules.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The compounds have to be arranged in the increasing order of boiling point and the reason for the different boiling points has to be explained.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom in the molecules.

The boiling points of aliphatic amines are higher than those of alkanes or halo alkanes of similar relative molecular mass due to intermolecular hydrogen bonding.

The N-H bond is more polar than the C-H bond but less polar than O-H bond.

Increasing order of boiling point of some organic compounds with similar molecular weight can be represented as follows,

Alkane < Ether < Alkyl halide < Amine < Ketone , aldehyde < Alcohol < Carboxylic acid

Answer 9

(b)

Interpretation Introduction

Interpretation:

The compounds have to be arranged in the increasing order of boiling point and the reason for the different boiling points has to be explained.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom in the molecules.

The boiling points of aliphatic amines are higher than those of alkanes or halo alkanes of similar relative molecular mass due to intermolecular hydrogen bonding.

The N-H bond is more polar than the C-H bond but less polar than O-H bond.

Increasing order of boiling point of some organic compounds with similar molecular weight can be represented as follows,

Alkane < Ether < Alkyl halide < Amine < Ketone , aldehyde < Alcohol < Carboxylic acid

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 17.1 - Identify the following molecules as a carboxylic...Ch. 17.1 - Prob. 17.2P Ch. 17.1 - Prob. 17.3P Ch. 17.1 - Prob. 17.4P Ch. 17.1 - Prob. 17.5P Ch. 17.1 - Prob. 17.6P Ch. 17.1 - In the following pairs of compounds, which would...Ch. 17.1 - Write both condensed and line structures for (a)...Ch. 17.1 - Prob. 17.9P Ch. 17.1 - Draw structures corresponding to these names: (a)...

Solution Summary: The author explains that hydrogen bonding occurs when the hydrogen is bonded to strong electronegative atom in the molecules. The boiling points of aliphatic amines are higher than those of alkanes.

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