Chapter 17, Problem 33P

Interpretation Introduction

Interpretation:

The steps that are involved in the preparation all the constitutional isomeric ethers having a molecular formula ${\text{C}}_{\text{4}}{\text{H}}_{\text{10}}\text{O}$ by using appropriate alcohols and considering Williamson ether synthesis is to be determined.

Concept Introduction:

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The constitutional isomers are also known as structural isomers and are referred to as those compounds are associated with the same molecular formula but different connectivity of atoms

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The reaction of an alkoxide ion with $1°$ alkyl halide through ${\text{S}}_{\text{N}}\text{2}$ mechanism to form ether is known as Williamson synthesis.

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The highest yields of products are obtained from less sterically hindered primary alkyl halides. Synthesis of ethers from this route is known as Williamson ether synthesis.