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Interpretation:
The given compounds has to be ranked from most reactive to least reactive towards nucleophilic addition.
Concept introduction:
The relative reactivity of carbonyl groups:
Carbonyl group is polar because oxygen is more electronegative than the carbon. As results carbonyl group is an electron deficient and it is an electrophile.
An
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Chapter 17 Solutions
Organic Chemistry; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card; Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)
- Rank the reactivity of the compounds below toward nucleophilic acyl substitution by writing the compounds' letters in the proper blanks in the box below. `NH CI Br CH3 CH3 A В C E rank compounds for acyl substitution reactivity most least reactive reactivearrow_forwardRank the compounds in each group in order of increasing reactivity in nucleophilic acyl substitution. C6H5CO2CH3, C6H5COCl, C6H5CONH2arrow_forwardRank the following compounds in order of increasing reactivity in nucleophilic addition.arrow_forward
- Rank the following compounds in order of increasing reactivity in a substitution reaction with −CN as nucleophile.arrow_forwardRank the compounds in each group in order of increasing reactivity toward nucleophilic attack.arrow_forwardRank the following esters in order of decreasing reactivity in the first slow step of a nucleophilic acyl substitution reaction (formation of the tetrahedral intermediate):Rank the same esters in order of decreasing reactivity in the second slow step of a nucleophilic acyl substitution reaction (collapse of the tetrahedral intermediate).arrow_forward
- Classify each of the following species as a nucleophile or an electrophile:arrow_forwardRank the following esters from most reactive to least reactive in the first slow step of a nucleophilic acyl substitution reaction (formation of the tetrahedral intermediate): Rank the same esters from most reactive to least reactive in the second slow step of a nucleophilic acyl substitution reaction (collapse of the tetrahedral intermediate).arrow_forwardRank the following compounds in order of increasing reactivity towards nucleophilic addition (most to least reactive). Provide a brief explanation for your choice. i) H ii) H iii) CH3arrow_forward
- Rank group of compounds from most reactive to least reactive toward electrophilic aromatic substitution: :- benzene, benzoic acid, phenol, propylbenzenearrow_forwardElectrophilic aromatic substitution usually occurs at the 1-position of naphthalene, also called the a position. Predict themajor products of the reactions of naphthalene with the following reagents. f) fuming sulfuric acidarrow_forwardRank the following carbonyl compounds in order or reactivity towards nucleophilic attackarrow_forward
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