Concept explainers
(a)
Interpretation:
Product formed when ethyl benzoate reacts with the given reagent has to be drawn.
Concept Introduction:
Ester Hydrolysis: Ester hydrolysis can be caused by acid and base.
Saponification: Ester hydrolysis taking place in presence of base such as
Acid-catalyzed hydrolysis: In presence of strong acid such as
(a)
Explanation of Solution
The synthesis of product transformation is shown below.
The ethyl benzoate (A) is reacted with sodium hydroxide in presence of basic conditions which corresponding yields the product (B). In this reaction addition and elimination process was occurred.
(b)
Interpretation:
Product formed when ethyl benzoate reacts with the given reagent has to be drawn.
Concept Introduction:
Ester Hydrolysis: Ester hydrolysis can be caused by acid and base.
Saponification: Ester hydrolysis taking place in presence of base such as
Acid-catalyzed hydrolysis: In presence of strong acid such as
(b)
Explanation of Solution
The synthesis of product transformation is shown below.
The ethyl benzoate (A) is undergoes for simple acid catalyzed hydrolysis, followed by heating to give a target compound (B), which is a benzoic acid.
(c)
Interpretation:
Product formed when ethyl benzoate reacts with the given reagent has to be drawn.
Concept Introduction:
Amide: One
Amide Formation: Amide is formed when a carboxylic acid reacts with an
- Primary amide is produce when a carboxylic acid reacts with ammonia.
- Secondary and tertiary amide is produce when a carboxylic acid reacts with primary and secondary amine respectively.
(c)
Explanation of Solution
The synthesis of product transformation is shown below.
The ethyl benzoate (A) is reacted with n-butylamine in presence of basic conditions which corresponding yields the product (B).
(d)
Interpretation:
Product formed when ethyl benzoate reacts with the given reagent has to be drawn.
Concept Introduction:
Diisobutylaluminium hydride (DIBALH): It is prepared by refluxing triisobutylaluminium in the solvent heptane.
DIBAL-H: is a strong reducing reagent most
DIBAL-H is a selective reagent (like,
(d)
Explanation of Solution
The synthesis of product transformation is shown below.
The equal amount of ethyl benzoate (A) is reacted with Diisobutylaluminium hydride (DIBALH) under dry ice conditions at
(e)
Interpretation:
Product formed when ethyl benzoate reacts with the given reagent has to be drawn.
Concept Introduction:
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like
LAH Reduction: The saturated/unsaturated aldehyde and ketones in the presence of sodium metal in LAH and carbonyl compound produced saturated alcohols. The keto group involves in the reduction process of LAH, this end up reducing to give the alcohols.
(e)
Explanation of Solution
The synthesis of product transformation is shown below.
The ethyl benzoate (A) undergoes for LAH reduction process followed by simple hydrolysis workup method to give a target product (B). The obtained product namely benzyl alcohol.
(f)
Interpretation:
Product formed when ethyl benzoate reacts with the given reagent has to be drawn.
Concept Introduction:
Alkyl or aryl magnesium halides (
Synthesis of Grignard reagent is shown below,
Acid Catalyzed Hydration Reaction: The reaction involves breaking of
(f)
Explanation of Solution
The synthesis of product transformation is shown below.
Two equivalents of Grignard reagent (A) is reacted with hydrogen chloride and fallowed by hydrolysis workup method, which corresponding yields the triphenyl methanol (B) it is a target molecule.
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Chapter 18 Solutions
OWLv2 with MindTap Reader, 1 term (6 months) Printed Access Card for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition
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