(a) Interpretation: The preparation of the p - nitroanisole from p - nitrophenol is to be stated. Concept introduction: The nucleophilic substitution reactions are the reactions in which a group is substituted by an nucleophile. The rate of reaction depends upon the nucleophilicity and concentration of the nucleophile. The S N 2 reaction is a nucleophilic substitution bimolecular reaction in which the addition of nucleophile and elimination of a leaving group takes place simultaneously. The rate of reaction depends upon both the substrate and reactant in the rate law equation.

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Answer 1

Question

Chapter 18, Problem 18.31P

Interpretation Introduction

(a)

Interpretation:

The preparation of the p- nitroanisole from p- nitrophenol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which a group is substituted by an nucleophile. The rate of reaction depends upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular reaction in which the addition of nucleophile and elimination of a leaving group takes place simultaneously. The rate of reaction depends upon both the substrate and reactant in the rate law equation.

Interpretation Introduction

(b)

Interpretation:

The preparation of the 2- phenoxyethanol from phenol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which a group is substituted by an nucleophile. The rate of reaction depends upon the nucleophilicity and concentration of the i nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular reaction in which the addition of nucleophile and elimination of a leaving group takes place simultaneously. The rate of reaction depends upon both the substrate and reactant in the rate law equation.

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(a) Although phenoxide ion has more number of resonating structures than carboxylate ion, carboxylic acid is a stronger acid than phenol. Give two reasons.(b) How will you bring about the following converstions?(i) Propanone to propane (ii) Benzoyl chloride to benzaldehyde(iii) Ethanal to but-2-enal

Explain the following statements. You must use chemical equations to justify your explanation. (ii) (I) Phenol is more acidic than cyclohexanol.

(a) Account for the following :(i) Propanal is more reactive than propanone towards nucleophilic reagents.(ii) Electrophilic substitution in benzoic acid takes place at meta position.(iii) Carboxylic acids do not give characteristic reactions of carbonyl group.(b) Give simple chemical test to distinguish between the following pairs of compounds:(i) Acetophenone and benzaldehyde(ii) Benzoic acid and ethylbenzoate.

Answer 2

Question

Chapter 18, Problem 18.31P

Interpretation Introduction

(a)

Interpretation:

The preparation of the p- nitroanisole from p- nitrophenol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which a group is substituted by an nucleophile. The rate of reaction depends upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular reaction in which the addition of nucleophile and elimination of a leaving group takes place simultaneously. The rate of reaction depends upon both the substrate and reactant in the rate law equation.

Interpretation Introduction

(b)

Interpretation:

The preparation of the 2- phenoxyethanol from phenol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which a group is substituted by an nucleophile. The rate of reaction depends upon the nucleophilicity and concentration of the i nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular reaction in which the addition of nucleophile and elimination of a leaving group takes place simultaneously. The rate of reaction depends upon both the substrate and reactant in the rate law equation.

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Answer 3

Question

Chapter 18, Problem 18.31P

Interpretation Introduction

(a)

Interpretation:

The preparation of the p- nitroanisole from p- nitrophenol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which a group is substituted by an nucleophile. The rate of reaction depends upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular reaction in which the addition of nucleophile and elimination of a leaving group takes place simultaneously. The rate of reaction depends upon both the substrate and reactant in the rate law equation.

Interpretation Introduction

(b)

Interpretation:

The preparation of the 2- phenoxyethanol from phenol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which a group is substituted by an nucleophile. The rate of reaction depends upon the nucleophilicity and concentration of the i nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular reaction in which the addition of nucleophile and elimination of a leaving group takes place simultaneously. The rate of reaction depends upon both the substrate and reactant in the rate law equation.

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Answer 4

Question

Chapter 18, Problem 18.31P

Interpretation Introduction

(a)

Interpretation:

The preparation of the p- nitroanisole from p- nitrophenol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which a group is substituted by an nucleophile. The rate of reaction depends upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular reaction in which the addition of nucleophile and elimination of a leaving group takes place simultaneously. The rate of reaction depends upon both the substrate and reactant in the rate law equation.

Interpretation Introduction

(b)

Interpretation:

The preparation of the 2- phenoxyethanol from phenol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which a group is substituted by an nucleophile. The rate of reaction depends upon the nucleophilicity and concentration of the i nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular reaction in which the addition of nucleophile and elimination of a leaving group takes place simultaneously. The rate of reaction depends upon both the substrate and reactant in the rate law equation.

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Answer 5

Chapter 18, Problem 18.31P

Interpretation Introduction

(a)

Interpretation:

The preparation of the p- nitroanisole from p- nitrophenol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which a group is substituted by an nucleophile. The rate of reaction depends upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular reaction in which the addition of nucleophile and elimination of a leaving group takes place simultaneously. The rate of reaction depends upon both the substrate and reactant in the rate law equation.

Interpretation Introduction

(b)

Interpretation:

The preparation of the 2- phenoxyethanol from phenol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which a group is substituted by an nucleophile. The rate of reaction depends upon the nucleophilicity and concentration of the i nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular reaction in which the addition of nucleophile and elimination of a leaving group takes place simultaneously. The rate of reaction depends upon both the substrate and reactant in the rate law equation.

Answer 6

Chapter 18, Problem 18.31P

Interpretation Introduction

(a)

Interpretation:

The preparation of the p- nitroanisole from p- nitrophenol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which a group is substituted by an nucleophile. The rate of reaction depends upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular reaction in which the addition of nucleophile and elimination of a leaving group takes place simultaneously. The rate of reaction depends upon both the substrate and reactant in the rate law equation.

Answer 7

Chapter 18, Problem 18.31P

Interpretation Introduction

(a)

Interpretation:

The preparation of the p- nitroanisole from p- nitrophenol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which a group is substituted by an nucleophile. The rate of reaction depends upon the nucleophilicity and concentration of the nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular reaction in which the addition of nucleophile and elimination of a leaving group takes place simultaneously. The rate of reaction depends upon both the substrate and reactant in the rate law equation.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The preparation of the 2- phenoxyethanol from phenol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which a group is substituted by an nucleophile. The rate of reaction depends upon the nucleophilicity and concentration of the i nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular reaction in which the addition of nucleophile and elimination of a leaving group takes place simultaneously. The rate of reaction depends upon both the substrate and reactant in the rate law equation.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The preparation of the 2- phenoxyethanol from phenol is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which a group is substituted by an nucleophile. The rate of reaction depends upon the nucleophilicity and concentration of the i nucleophile.

The SN2 reaction is a nucleophilic substitution bimolecular reaction in which the addition of nucleophile and elimination of a leaving group takes place simultaneously. The rate of reaction depends upon both the substrate and reactant in the rate law equation.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 18 - Prob. 18.1P Ch. 18 - Prob. 18.2P Ch. 18 - Prob. 18.3P Ch. 18 - Prob. 18.4P Ch. 18 - Prob. 18.5P Ch. 18 - Prob. 18.6P Ch. 18 - Prob. 18.7P Ch. 18 - Prob. 18.8P Ch. 18 - Prob. 18.9P Ch. 18 - Prob. 18.10P

Solution Summary: The author explains the nucleophilic substitution reactions, which are the reactions in which a group is substituted by an

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Chapter 18 Solutions