Student Solutions Manual for Ball's Physical Chemistry, 2nd
Student Solutions Manual for Ball's Physical Chemistry, 2nd
2nd Edition
ISBN: 9798214169019
Author: David W. Ball
Publisher: Cengage Learning US
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Chapter 18, Problem 18.3E
Interpretation Introduction

Interpretation:

The values of qnuc for tin isotopes are to be determined. The number of different values is to be stated.

Concept introduction:

Different linearly independent wavefunctions that have same energy are called degenerate. This is expressed in terms of degeneracy. If two functions are having same energy then they are called doubly degenerate and so on. The degeneracy for nuclear state is given as,

g1=2I+1

Where,

I represents the nuclear spin.

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Consider an electron in the spin-state σ = [+ [α + ẞ]. (a) Is σ an eigenfunction of Ŝ²? If yes, what is the eigenvalue and what is the corresponding spin magnitude? If no, what is the expectation value? (b) Is σ an eigenfunction of S.? If yes, what is the eigenvalue? If no, what is the expectation value?
According to the shell model, the spin-parity of the ground state of 0-18 (Z=8, A=15) nucleus is: O Nuclear spin: 1, parity: + Nuclear spin: 0, parity: + Nuclear spin: 2 parity: + Nuclear spin: 2 parity: - Ο Ο Ο Ο 13
What do you understand by estimation? Justify that using higher values of Cl gives better estimations.

Chapter 18 Solutions

Student Solutions Manual for Ball's Physical Chemistry, 2nd

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