Concept explainers
a)
Interpretation:
The expression ad value of
Concept Introduction:
In all electrochemical cells, oxidation occurs at anode and reduction occurs at cathode.
An anode is indicated by negative sign and cathode is indicated by the positive sign.
Electrons flow in the external circuit from the anode to the cathode.
In the electrochemical cells two half cells are connected with salt bridge. It allows the cations and anions to move between the two half cells.
Standard potential
If
If
The relation between standard cell potential and equilibrium constant is as follows.
b)
Interpretation:
The expression ad value of
Concept Introduction:
Refer to (a)
c)
Interpretation:
The expression ad value of
Concept Introduction:
Refer to (a)
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Chemistry: Principles and Practice
- Give the notation for a voltaic cell whose overall cell reaction is Mg(s)+2Ag+(aq)Mg2+(aq)+2Ag(s) What are the half-cell reactions? Label them as anode or cathode reactions. What is the standard cell potential of this cell?arrow_forwardConsider the following cell running under standard conditions: Fe(s)Fe2+(aq)Al3+(aq)Al(s) a Is this a voltaic cell? b Which species is being reduced during the chemical reaction? c Which species is the oxidizing agent? d What happens to the concentration of Fe3+(aq) as the reaction proceeds? e How does the mass of Al(s) change as the reaction proceeds?arrow_forwardThe voltaic cell is represented as Zn(s)Zn2+(1.0M)Cu2+(1.0M)Cu(s) Which of the following statements is not true of this cell? a The mass of the zinc electrode, Zn(s), decreases as the cell runs. b The copper electrode is the anode. c Electrons flow through the external circuit from the zinc electrode to the copper electrode. d Reduction occurs at the copper electrode as the cell runs. e The concentration of Cu2+ decreases as the cell runs.arrow_forward
- Calculate the standard cell potential of the following cell at 25C. Sn(s)Sn2+(aq)I2(aq)I(aq)arrow_forwardWhat is the standard cell potential you would obtain from a cell at 25C using an electrode in which Hg22+(aq) is in contact with mercury metal and an electrode in which an aluminum strip dips into a solution of Al3+(aq)?arrow_forwardCalculate the standard cell potential of the cell corresponding to the oxidation of oxalic acid, H2C2O4, by permanganate ion. MnO4. 5H2C2O4(aq)+2MnO4(aq)+6H+(aq)10CO2(g)+2Mn2+(aq)+8H2O(l) See Appendix C for free energies of formation: Gf for H2C2O4(aq) is 698 kJ.arrow_forward
- Consider the following galvanic cell: Calculate the concentrations of Ag+(aq) and Ni2+(aq) once the cell is dead.arrow_forwardCalculate the standard cell potential at 25C for the following cell reaction from standard free energies of formation (Appendix C). Mg(s)+2Ag+(aq)Mg2+(aq)+2Ag(s)arrow_forwardIn principle, a battery could be made from aluminum metal and chlorine gas. (a) Write a balanced equation for the reaction thatwould occur in a battery using Al3+(aq) | Al(s) andCl2(g) | Cl(aq) half-cells. (b) Identify the half-reaction at the anode and at the cathode. Do electrons flow from the Al electrode when thecell does work? Explain. (c) Calculate the standard potential, Ecell, for the battery.arrow_forward
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