Products of given reactions has to be predicted. Concept introduction: Given set of conditions gives a final product of reaction through a series of steps. Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction. Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction. A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product. Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction. Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product. A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 18, Problem 48P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

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Chemistry Draw the product formed when phenylacetaldehyde (C6H5CH2CHO) is treated with reach reagent: f. (CH3)2CHNH2, mild acid g. (CH3CH2)2NH, mild acid h. CH3CH2OH (excess), H+ i. piperidine, mild acid j. HOCH2CH2OH, H+

1. Reaction of pyridine with Br2 yields what? 2. Reaction of pyrrolidine with Br2 in the presence of ethanol yields what?

Draw the products formed when benzoyl chloride (C6H5COCl) is treated with each nucleophile: (a) H2O, pyridine; (b) CH3COO-; (c) NH3 (excess); (d) (CH3)2NH (excess).

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 18, Problem 48P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 18, Problem 48P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 18, Problem 48P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

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Check out a sample textbook solution

See solution

Answer 5

Chapter 18, Problem 48P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 6

Chapter 18, Problem 48P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 7

Chapter 18, Problem 48P

(a)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 8

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 9

(b)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 10

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 11

(c)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 12

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 13

(d)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 14

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 15

(e)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 16

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 17

(f)

Interpretation Introduction

Interpretation: Products of given reactions has to be predicted.

Concept introduction: Given set of conditions gives a final product of reaction through a series of steps.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Carboxylic acid undergoes α substitution by Hell Volhard Zelinsky reaction.

A strong base like LDA abstracts α proton from a carbon atom of acetone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

Ester reacts with a base to form an enolate ion which attacks alkyl bromide to form an alkylated product. Hydrolysis and decarboxylation take place to form a product.

A strong base like LDA abstracts α proton from a carbon atom of the ketone to form an enolate ion. Enolate ion attacks on carbonyl of ester to form a product.

Answer 18

Expert Solution & Answer

Answer 19

Expert Solution & Answer

Answer 20

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Answer 21

Ch. 18.1 - Prob. 1P Ch. 18.1 - Prob. 2P Ch. 18.1 - Prob. 3P Ch. 18.1 - Prob. 4P Ch. 18.1 - PROBLEM 5♦ List the compounds in each of the...Ch. 18.2 - Explain why 92% of 2,4-pemtanedione exists as the...Ch. 18.3 - Draw the enol tautomers for each of the following...Ch. 18.3 - Prob. 8P Ch. 18.4 - Prob. 9P Ch. 18.4 - Prob. 10P

Solution Summary: The author explains that Ester reacts with a base to form an enolate ion which undergoes intramolecular reaction.

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Chapter 18 Solutions