Physics for Scientists and Engineers, 4th Ed + Masteringphysics: Chapters 20-35
4th Edition
ISBN: 9780136139249
Author: Douglas C. Giancoli
Publisher: PEARSON EDUCATION (COLLEGE)
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Chapter 18, Problem 70GP
To determine
The percent error in measurement of van der Waals pressure and the ideal gas pressure.
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Suppose that a gas obeys at low pressures the equation PVm = RT + (A+ B/T2)P where A and B are constants independent of pressure and temperature, and Vm is the molar volume. Derive the expression for the change in enthalpy which will accompany the expansion of n moles of gas from a pressure P1to a pressure P2 at temperature T.
Only answer letters (d) and (e)
a) Using the Maxwell-Boltzmann function, calculate the fraction of argon gas molecules with a speed of 305 m/s at 500 K. (ans: 0.0014)
b) If the system in (a) has 0.46 moles of argon gas, how many molecules have the speed of 305 m/s? (ans: 6.44 x 10-4)
c) Calculate the values of vmp, vavg, and vrms for xenon gas at 298 K. (ans: Vmp=194.2 m/s , Vavg=219.2 m/s , Vrms=237.8 m/s)
d) From the values calculated in (c), label the Boltzmann distribution plot with the approximate locations of vmp, v avg, and vrms
e) What will have a larger speed distribution, helium at 500 K or argon at 300 K? Helium at 300 K or argon at 500 K? Argon at 400 K or argon at 1000 K?
Using the ideal gas law, PV = nRT, determine the volume 200 lbs of hydrogen would occupy at 180 degrees F and a pressure of 100 psig? Assume the constant “R” is 10.731 Ft3PSIA/0R lb mole and the molecular weight of H2 is 2 lbs./mole.
Chapter 18 Solutions
Physics for Scientists and Engineers, 4th Ed + Masteringphysics: Chapters 20-35
Ch. 18.1 - In a mixture of the gases oxygen and helium, which...Ch. 18.1 - Now you can return to the Chapter-Opening...Ch. 18.1 - If you double the volume of a gas while keeping...Ch. 18.1 - By what factor must the absolute temperature...Ch. 18.4 - As the air warms up in the afternoon, how would...Ch. 18 - Why doesnt the size of different molecules enter...Ch. 18 - When a gas is rapidly compressed (say, by pushing...Ch. 18 - In Section 181 we assumed the gas molecules made...Ch. 18 - Explain in words how Charless law follows from...Ch. 18 - Prob. 5Q
Ch. 18 - As you go higher in the Earths atmosphere, the...Ch. 18 - Prob. 7QCh. 18 - Is temperature a macroscopic or microscopic...Ch. 18 - Explain why the peak of the curve for 310 K in...Ch. 18 - Escape velocity for the Earth refers to the...Ch. 18 - Prob. 11QCh. 18 - If the pressure in a gas is doubled while its...Ch. 18 - What everyday observation would tell you that not...Ch. 18 - Prob. 14QCh. 18 - Alcohol evaporates more quickly than water at room...Ch. 18 - Explain why a hot humid day is far more...Ch. 18 - Is it possible to boil water at room temperature...Ch. 18 - What exactly does it mean when we say that oxygen...Ch. 18 - A length of thin wire is placed over a block of...Ch. 18 - Consider two days when the air temperature is the...Ch. 18 - (a) Why does food cook faster in a pressure...Ch. 18 - How do a gas and a vapor differ?Ch. 18 - (a) At suitable temperatures and pressures, can...Ch. 18 - Why does dry ice not last long at room...Ch. 18 - Under what conditions can liquid CO2 exist? Be...Ch. 18 - Why does exhaled air appear as a little white...Ch. 18 - Prob. 27QCh. 18 - Prob. 1PCh. 18 - Prob. 2PCh. 18 - (I) By what factor will the rms speed of gas...Ch. 18 - (I) A gas is at 20C. To what temperature must it...Ch. 18 - (I) What speed would a 1.0-g paper clip have if it...Ch. 18 - (I) A 1.0-mol sample of hydrogen gas has a...Ch. 18 - (I) Twelve molecules have the following speeds,...Ch. 18 - (II) The rms speed of molecules in a gas at 20.0C...Ch. 18 - (II) If the pressure in a gas is tripled while its...Ch. 18 - Prob. 10PCh. 18 - (II) Show that for a mixture of two gases at the...Ch. 18 - (II) What is the rms speed of nitrogen molecules...Ch. 18 - (II) (a) For an ideal gas at temperature T show...Ch. 18 - Prob. 14PCh. 18 - Prob. 15PCh. 18 - Prob. 16PCh. 18 - Prob. 17PCh. 18 - Prob. 18PCh. 18 - Prob. 19PCh. 18 - (I) A group of 25 particles have the following...Ch. 18 - Prob. 21PCh. 18 - (I) CO2 exists in what phase when the pressure is...Ch. 18 - (I) (a) At atmospheric pressure, in what phases...Ch. 18 - Prob. 25PCh. 18 - Prob. 26PCh. 18 - Prob. 27PCh. 18 - Prob. 28PCh. 18 - Prob. 29PCh. 18 - Prob. 30PCh. 18 - (II) If the air pressure at a particular place in...Ch. 18 - (II) What is the mass of water in a closed room...Ch. 18 - Prob. 33PCh. 18 - Prob. 34PCh. 18 - (II) A pressure cooker is a sealed pot designed to...Ch. 18 - (II) When using a mercury barometer (Section 136),...Ch. 18 - (II) If the humidity is 45% at 30.0C, what is the...Ch. 18 - Prob. 38PCh. 18 - Prob. 40PCh. 18 - (II) For oxygen gas, the van der Waals equation of...Ch. 18 - Prob. 44PCh. 18 - (II) At about what pressure would the mean free...Ch. 18 - Prob. 46PCh. 18 - (II) A very small amount of hydrogen gas is...Ch. 18 - Prob. 48PCh. 18 - Prob. 49PCh. 18 - Prob. 50PCh. 18 - Prob. 51PCh. 18 - Prob. 53PCh. 18 - Prob. 54PCh. 18 - Prob. 55PCh. 18 - A sample of ideal gas must contain at least N =...Ch. 18 - In outer space the density of matter is about one...Ch. 18 - Calculate approximately the total translational...Ch. 18 - (a) Estimate the rms speed of an amino acid, whose...Ch. 18 - The escape speed from the Earth is 1.12 104 m/s,...Ch. 18 - Prob. 61GPCh. 18 - Prob. 62GPCh. 18 - Consider a container of oxygen gas at a...Ch. 18 - In humid climates, people constantly dehumidify...Ch. 18 - Prob. 65GPCh. 18 - Prob. 66GPCh. 18 - Prob. 67GPCh. 18 - At room temperature, it takes approximately 2.45 ...Ch. 18 - Calculate the total water vapor pressure in the...Ch. 18 - Prob. 70GPCh. 18 - The density of atoms, mostly hydrogen, in...Ch. 18 - Prob. 72GPCh. 18 - A sauna has 8.5 m3 of air volume, and the...Ch. 18 - Prob. 74GPCh. 18 - Prob. 75GP
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