Concept explainers
(a)
Interpretation:
The complete equation for the hydrolysis of the given amide in concentrated aqueous
Concept introduction:
Amide hydrolysis in aqueous base:
A carboxylate salt and ammonia or an
For each mole of amide, one mole of base is required.
(b)
Interpretation:
The complete equation for the hydrolysis of the given amide in concentrated aqueous
Concept introduction:
Amide hydrolysis in aqueous base:
A carboxylate salt and ammonia or an amine will be the product of amide hydrolysis in aqueous base.
For each mole of amide, one mole of base is required.
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Chapter 18 Solutions
ORGANIC CHEMISTRY-OWL V2 ACCESS
- 8 (Chemical Connections 19C) Once it has been opened, and particularly if it has been left open to the air, a bottle of aspirin may develop a vinegar-like odor. Explain how this might happen.arrow_forwardName (by the common system of nomenclature) the amine (or ammonia) that is formed by the basic hydrolysis of the following acid amide:arrow_forwardWrite equations for the hydrolysis of these amides in concentrated aqueous HCl. Show all products as they exist in aqueous HCl and the number of moles of HCl required for hydrolysis of each amidearrow_forward
- Draw the structures of the products when each of the following amides undergo hydrolysis with NaOH. You may want to reference (Page) Section 18.6 while completing this problem. ▼ CH3 0 CH,—CH,—CH—C—NH, Draw the molecules on the canvas by choosing buttons from the Tools (for bonds and charg www NN [1] Submit Part B Request Answer H 120 EXP CONT + Marvin JS by ChemAxon • & H H 120 EXP CONT C N O S CI Br - PFL O CH₂ CH3 CH3-CH₂-CH₂-C-N-CH₂-CH3 Draw the molecules on the canvas by choosing buttons from the Tools (for bonds and charg Р H C Z Oarrow_forwardComplete equations for the hydrolysis of the amides in concentrated aqueous NaOH. Show all products as they exist in aqueous NaOH and the number of moles of NaOH required for hydrolysis of each amide.arrow_forwardCompare the table below by giving the structure and name of a primary (10), secondary(20), and tertiary(30) amine with molecular formula C3H9N. Primary amines can be prepared from amides by Hoffman's reaction. Write a general equation for the reaction and give reagents with reaction conditions for this reaction.arrow_forward
- 11. Write the chemical reaction for the acid hydrolysis of each amide sample. Include the 유 condensed structural formulas of the reactants and products. 11 CH3-C-NH₂ +H20+HCI CH3-C-OH + NH4+ CI- ACETAMIDE SO -NH2 +H20 T → 0 COOH + NH 3 11arrow_forwardDraw structural formulas for the two compounds you could use to prepare the amine shown by reductive amination. Please provide the correct answer.arrow_forwardWrite equations for the hydrolysis of these amides in concentrated aqueous HCl. Show all products as they exist in aqueous HCl and the number of moles of HCl required for hydrolysis of each amidearrow_forward
- Sodium borohydride used in the organic lab is a(n) amine carboxylic acid oxidizing agent reducing agentarrow_forwardExplain why CH3 CH2 CH2NH2 is a Brønsted base. Its water solutions are basic. All substances containing nitrogen atoms are Brønsted bases. This amine is a proton donor. This amine can ассеpt a proton from a proton donor.arrow_forwardWrite the products of the reaction of diphenhydramine (a base) with the acid HCI shown below. H COCH₂CH₂NCH3 + HC1 CH3 Consider the chemical reaction from the previous question. Are the reactants or products more soluble in water? Briefly explain.arrow_forward
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