Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393600681
Author: Gilbert
Publisher: W. W. Norton & Company
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What is an isomer? Name the isomers of the compound with the closed
formula C4H9CI. Which of these isomers can have a chiral structure?
Examine it from a stereochemical point of view
Palmitoleic acid, a fatty acid with various pharmaceutical
applications, is mainly obtained from macadamia nuts. The
condensed structural formula for a triacylglycerol containing
three palmitoleic acid units is provided below. Which of the
following statements is NOT true regarding this
triacylglycerol?
O
||
CH,−O−C–(CH,)–CH=CH—(CH2)5–CH3
O
||
CH−O−C−(CH2)–CH=CH–(CH,)5–CH3
O
CH,−O−C−(CH,)–CH=CH–(CH,)5–CH,
O
Its name is glyceryl tripalmitate or tripalmitin.
O It is most likely to be liquid at room temperature.
O It is an oil (not a fat).
O It contains 3 molecules of the same unsaturated fatty acid.
2-bromopentane is an optically active compound. Draw the two possible structures of optical
isomer and label the chiral center with an asterisk (*) in each of the optical isomer structure.
Chapter 19 Solutions
Chemistry: An Atoms-Focused Approach
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- Name the isomers of the compound with the closed formula C4H9Cl. Which of these isomers can have a chiral structure? Examine it from a stereochemical point of view.arrow_forwardAdenine and guanine are the members of a class of molecules known as purines; they have two rings in their structure. Thymine and cytosine, on the other hand, are pyrimidines and have only one ring in their structure. Predict which have larger dispersion forces in aqueous solution.arrow_forwardGlucose, C6H12O6, contains an aldehyde group but exist predominantly in the form of the cyclic hemiacetal show below. A cyclic hemiacetal is formed when the —OH group of one carbon bonds to the carbonyl group of another carbon. Identify which carbon provides the —OH group and which provides the —CHO? Give a functional isomer of glucose and draw its structure.arrow_forward
- Draw the structural isomers of C2H4BrCl and identify which of them has a chiral center.arrow_forwardThe structural formula for the open-chain form of galactose is CH Н—ҫ—ОН Но—С—н НО—С—Н Н—ҫ—ОН CH-ОН (a) Is this molecule a sugar? (b) How many chiral carbons are present in the molecule? (C) Draw the structure of the six-member-ring form of this molecule.arrow_forward1.Circle the organic the functional groups and name them. 2.Mark all chiral centers and determine the configuration of one of them.arrow_forward
- Indicate the chiral centers in the molecules.arrow_forwardFor example, alanine is a chiral amino acid that has two enantiomers: (+)-alanine and (-)-alanine. These two are optical isomers. NH2 NH2 4. One of the most important properties of chiral molecules in solution is their effect on plane- polarized light, this effect is called optical activity. -C H 2 COOH HOOC CH When an enantiomer rotates a plane-polarized light in the positive direction or clockwise, it is dextrorotary (+ or d), while for a negative direction or counterclockwise, it is levorotary (- or l) (+)-Alanine (-)-Alanine Alanine is a chiral amino acid that has two enantiomers: (+)-alanine and ()-alanine. These two are optical isomers.arrow_forwardOrganic Chemistry HW: CANNOT BE HAND DRAWN 2,6-dimethyloct-2-ene Provide a detailed typed explanation of Stereoisomers show the expanded structure of your molecule. Calculate the maximum number of possible stereoisomers of your molecule using the following formula: Maximum number of possible stereoisomers = 2n (where n= the number of chiral carbons in your molecule). This calculation does not include E- or Z- isomers for any compounds containing double bonds Type or using a computer program "draw" the possible stereoisomers of the molecule. Note that E-, Z- isomers of each stereoisomer are also possible and would not be accounted for by the formula above; draw any E- or Z- isomers.arrow_forward
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