Accidentally chewing on a stray fragment of aluminum foil can cause a sharp tooth pain if the aluminum comes in contact with an amalgam filling. The filling, an alloy of silver, tin, and mercury, acts as the cathode of a tiny galvanic cell, the aluminum behaves as the anode, and saliva serves as the electrolyte. When the aluminum and the filling come in contact, an
(a) Write balanced equations for the anode, cathode, and overall cell reactions.
(b) Write the Nernst equation in a form that applies at body temperature 37 °C.
(c) Calculate the cell voltage at 37 °C. You may assume that
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- You have 1.0 M solutions of Al(NO3)3 and AgNO3 along with Al and Ag electrodes to construct a voltaic cell. The salt bridge contains a saturated solution of KCl. Complete the picture associated with this problem by a writing the symbols of the elements and ions in the appropriate areas (both solutions and electrodes). b identifying the anode and cathode. c indicating the direction of electron flow through the external circuit. d indicating the cell potential (assume standard conditions, with no current flowing). e writing the appropriate half-reaction under each of the containers. f indicating the direction of ion flow in the salt bridge. g identifying the species undergoing oxidation and reduction. h writing the balanced overall reaction for the cell.arrow_forwardIdentify each statement as true or false. Rewrite each false statement to make it true. (a) Oxidation always occurs at the anode of an electrochemical cell. (b) The anode of a discharging voltaic cell is the site ofreduction and is negative. (c) Standard-state conditions for electrochemical cells are aconcentration of 1.0 M for dissolved species and a pressure of 1 bar for gases. (d) The potential of a voltaic cell does not change withtemperature. (e) All product-favored oxidation-reduction reactions have astandard cell potential Ecell, with a negative sign.arrow_forwardFor each reaction listed, determine its standard cell potential at 25 C and whether the reaction is spontaneous at standard conditions. (a) Mn(s)+Ni2+(aq)Mn2+(aq)+Ni(s) (b) 3Cu2+(aq)+2Al(s)2Al3+(aq)+3Cu(s) (c) Na(s)+LiNO3(aq)NaNO3(aq)+Li(s) (d) Ca(NO3)2(aq)+Ba(s)Ba(NO3)2(aq)+Ca(s)arrow_forward
- Zinc is produced by electrolytic refining. The electrolytic process, which is similar to that for copper, can be represented by the two half-reactions Zn(impure,s)Zn2++2eZn2++2eZn(pure,s) For this process, a voltage of 3.0 V is used. How many kilowatt hours are needed to produce one metric ton of pure zinc?arrow_forwardAn aqueous solution of an unknown salt of gold is electrolyzed by a current of 2.75 amps for 3.39 hours. The electroplating is carried out with an efficiency of 93.0%, resulting in a deposit of 21.221 g of gold. a How many faradays are required to deposit the gold? b What is the charge on the gold ions (based on your calculations)?arrow_forward
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