EBK GENERAL CHEMISTRY: THE ESSENTIAL CO
EBK GENERAL CHEMISTRY: THE ESSENTIAL CO
7th Edition
ISBN: 9780100257047
Author: Chang
Publisher: YUZU
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Chapter 19, Problem 19.33QP
Interpretation Introduction

Interpretation:

The ratio of [Cu2+] and [Zn2+] ion needed for spontaneity of the reaction was to be identified by using Figure 18.1.

Concept introduction:

For an electrochemical reaction to take place spontaneously the change in free energy must be negative. Change in free energy ΔG represents the maximum amount of useful work that can be obtained from the reaction and can be given by the following formula

ΔG=wmax

ΔG=nFEcell

Both n and F are positive quantities and ΔG is negative for a spontaneous process, so Ecell must be positive for a spontaneous process.

Ecell of the given cell can be calculated from the simplified Nernst equation.

Eocell=Eoreduction-Eooxidation

Ecell= Eocell-(0.0257n)ln[ox][red]

Eocell = standard potential of a cell

n = Number of electrons transferred in the cell reaction

[ox] = Concentration of the oxidation half

[red] = Concentration of the reduction half

In order to calculate the ratio of [Cu2+]/[Zn2+] for a spontaneous cell reaction Ecell was fixed as zero, because this is the point at which the reaction become spontaneous and Nernst equation can be modified as

0= Eocell-(0.0257n)ln[Cu2+][Zn2+]

To find: The ratio of [Cu2+]/[Zn2+] at which the given reaction can takes spontaneously

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Chapter 19 Solutions

EBK GENERAL CHEMISTRY: THE ESSENTIAL CO

Ch. 19.5 - Prob. 2PECh. 19.5 - Prob. 1RCCh. 19.7 - Prob. 1RCCh. 19.8 - Prob. 1RCCh. 19.8 - An aqueous solution of Mg(NO3)2 is electrolyzed....Ch. 19.8 - Prob. 2RCCh. 19.8 - Prob. 2PECh. 19.8 - Prob. 3RCCh. 19 - Prob. 19.1QPCh. 19 - Prob. 19.2QPCh. 19 - Prob. 19.3QPCh. 19 - Prob. 19.4QPCh. 19 - Prob. 19.5QPCh. 19 - Prob. 19.6QPCh. 19 - 19.7 What is the difference between the...Ch. 19 - Prob. 19.8QPCh. 19 - Prob. 19.9QPCh. 19 - Prob. 19.10QPCh. 19 - Prob. 19.11QPCh. 19 - Prob. 19.12QPCh. 19 - Prob. 19.13QPCh. 19 - 19.14 Which of the following reagents can oxidize...Ch. 19 - 19.15 Consider the following half-reactions: (aq)...Ch. 19 - 19.16 Predict whether the following reactions...Ch. 19 - Prob. 19.17QPCh. 19 - Prob. 19.18QPCh. 19 - Prob. 19.19QPCh. 19 - Prob. 19.20QPCh. 19 - Prob. 19.21QPCh. 19 - Prob. 19.22QPCh. 19 - Prob. 19.23QPCh. 19 - Prob. 19.24QPCh. 19 - Prob. 19.25QPCh. 19 - Prob. 19.26QPCh. 19 - Prob. 19.27QPCh. 19 - Prob. 19.28QPCh. 19 - Prob. 19.29QPCh. 19 - Prob. 19.30QPCh. 19 - Prob. 19.31QPCh. 19 - Prob. 19.33QPCh. 19 - Prob. 19.34QPCh. 19 - 19.35 Explain the differences between a primary...Ch. 19 - Prob. 19.36QPCh. 19 - Prob. 19.37QPCh. 19 - Prob. 19.38QPCh. 19 - Prob. 19.39QPCh. 19 - Prob. 19.40QPCh. 19 - Prob. 19.41QPCh. 19 - Prob. 19.42QPCh. 19 - 19.43 What is the difference between a galvanic...Ch. 19 - Prob. 19.44QPCh. 19 - Prob. 19.45QPCh. 19 - Prob. 19.46QPCh. 19 - Prob. 19.47QPCh. 19 - Prob. 19.48QPCh. 19 - Prob. 19.49QPCh. 19 - Prob. 19.50QPCh. 19 - 19.51 Calculate the amounts of Cu and Br2 produced...Ch. 19 - Prob. 19.52QPCh. 19 - Prob. 19.53QPCh. 19 - Prob. 19.54QPCh. 19 - 19.55 What is the hourly production rate of...Ch. 19 - Prob. 19.56QPCh. 19 - Prob. 19.57QPCh. 19 - Prob. 19.58QPCh. 19 - Prob. 19.59QPCh. 19 - Prob. 19.60QPCh. 19 - Prob. 19.61QPCh. 19 - Prob. 19.62QPCh. 19 - Prob. 19.63QPCh. 19 - Prob. 19.64QPCh. 19 - Prob. 19.65QPCh. 19 - 19.66 A sample of iron ore weighing 0.2792 g was...Ch. 19 - Prob. 19.67QPCh. 19 - Prob. 19.68QPCh. 19 - Prob. 19.69QPCh. 19 - Prob. 19.70QPCh. 19 - Prob. 19.71QPCh. 19 - Prob. 19.72QPCh. 19 - Prob. 19.73QPCh. 19 - Prob. 19.74QPCh. 19 - Prob. 19.75QPCh. 19 - Prob. 19.76QPCh. 19 - Prob. 19.77QPCh. 19 - Prob. 19.78QPCh. 19 - Prob. 19.79QPCh. 19 - Prob. 19.80QPCh. 19 - Prob. 19.81QPCh. 19 - Prob. 19.82QPCh. 19 - Prob. 19.83QPCh. 19 - Prob. 19.84QPCh. 19 - Prob. 19.86QPCh. 19 - Prob. 19.87QPCh. 19 - Prob. 19.88QPCh. 19 - Prob. 19.89QPCh. 19 - Prob. 19.90QPCh. 19 - Prob. 19.91QPCh. 19 - Prob. 19.92QPCh. 19 - Prob. 19.93QPCh. 19 - Prob. 19.94QPCh. 19 - Prob. 19.95QPCh. 19 - Prob. 19.96QPCh. 19 - Prob. 19.97QPCh. 19 - Prob. 19.98QPCh. 19 - Prob. 19.99QPCh. 19 - Prob. 19.100QPCh. 19 - Prob. 19.101QPCh. 19 - 19.102 The magnitudes (but not the signs) of the...Ch. 19 - Prob. 19.103QPCh. 19 - Prob. 19.104QPCh. 19 - Prob. 19.105QPCh. 19 - Prob. 19.106QPCh. 19 - Prob. 19.107QPCh. 19 - Prob. 19.108QPCh. 19 - Prob. 19.109QPCh. 19 - Prob. 19.110QPCh. 19 - 19.111 A spoon was silver-plated electro lyrically...Ch. 19 - Prob. 19.112QPCh. 19 - Prob. 19.113QPCh. 19 - Prob. 19.114QPCh. 19 - Prob. 19.115QPCh. 19 - Prob. 19.116QPCh. 19 - Prob. 19.117QPCh. 19 - Prob. 19.118QPCh. 19 - Prob. 19.119QPCh. 19 - Prob. 19.120QPCh. 19 - Prob. 19.121SPCh. 19 - Prob. 19.122SPCh. 19 - Prob. 19.123SPCh. 19 - Prob. 19.124SPCh. 19 - Prob. 19.125SPCh. 19 - Prob. 19.126SPCh. 19 - Prob. 19.128SPCh. 19 - Prob. 19.129SPCh. 19 - Prob. 19.130SP
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