(a)
Interpretation:
How to carry out the given transformation is to be shown.
Concept introduction:
There are several oxidizing agents which are used to oxidize primary alcohols into corresponding acids. Chromic acid will oxidize a primary alcohol to a
(b)
Interpretation:
The product of the given reaction is to be predicted.
Concept introduction:
Pyridinium chlorochromate (PCC) is a partial oxidizing agent. Oxidation of a primary alcohol by pyridinium chlorochromate (PCC) stops at the aldehyde because the reaction takes place in a nonaqueous medium. Pyridinium chlorochromate (PCC) oxidizes a primary alcohol to an aldehyde and a secondary alcohol to a ketone.
(c)
Interpretation:
How to carry out the given transformation is to be shown.
Concept introduction:
There are several oxidizing agents which are used to oxidize secondary alcohols into ketones. Chromic acid will oxidize a primary alcohol to a carboxylic acid or a secondary alcohol to a ketone. Chromic acid is prepared by dissolving sodium dichromate in an acidic solution. Like chromic acid, potassium permanganate is also used as an oxidizing agent. When treated with a basic solution of potassium permanganate (
(d)
Interpretation:
The product of the given reaction is to be predicted.
Concept introduction:
Pyridinium chlorochromate (PCC) is a partial oxidizing agent. Oxidation of a primary alcohol by pyridinium chlorochromate (PCC) stops at the aldehyde because the reaction takes place in a nonaqueous medium. Pyridinium chlorochromate (PCC) oxidizes a primary alcohol to an aldehyde and a secondary alcohol to a ketone.
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Chapter 19 Solutions
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