Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
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Textbook Question
Chapter 2, Problem 2.33P
Why are the ionization energies of the alkali metals in the order
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what are likely possibilies for X if Xn + Cl -> XCl2
can you help explain how to solve this? Would it be any element in the 2nd s2 row (Be, Mg, Ca, Sr, Ba, Ra)?
The electron affinities, in kJ>mol, for the group 1B and group2B metals are as follows:
(a) Why are the electron affinities of the group 2B elementsgreater than zero? (b) Why do the electron affinities of thegroup 1B elements become more negative as we move downthe group? [Hint: Examine the trends in the electron affinitiesof other groups as we proceed down the periodic table.]
What is the valence electron configu.ration for Group SA (lS) elements?Metallic character increases when going down a group. Give some examples illustrating how Bi and Sbhave metallic characteristics not associated with N, P,and As. Elemental nitrogen exists as N2 whereas in the gas phase the elements phosphorus, arsenic, and antimony consist of P4' As4, and Sb4 molecules, respectively.Give a possible reason for" this difference between N2 and the other Group SA (lS) elements. White phosphorus is much more reactive than black or red phosphorus. Explain.
Chapter 2 Solutions
Inorganic Chemistry
Ch. 2.1 - Determine the energy of the transition from nh=3...Ch. 2.2 - Describe the angular nodal surfaces for a dz2...Ch. 2.2 - Prob. 2.3ECh. 2.2 - A third possible state for the p4 configuration...Ch. 2.2 - A nitrogen atom, with three 2p electrons, could...Ch. 2.2 - Calculate the effective nuclear charge on a 5s,...Ch. 2.2 - Calculate the effective nuclear charge on a 7s,...Ch. 2.3 - Explain why all three graphs in Figure 2.14 have...Ch. 2 - Determine the de Brogue wavelength of a. an...Ch. 2 - Using the equation E=RH(1221nh2) determine the...
Ch. 2 - The transition from the n=7 to the n=2 level of...Ch. 2 - Emissions are observed at wavelengths of 383.65...Ch. 2 - What is the least amount of energy that can be...Ch. 2 - Hydrogen atom emission spectra measured from the...Ch. 2 - The Rydberg constant equation has two terms that...Ch. 2 - For the 3pz and 4dxz hydrogen-like atomic...Ch. 2 - Repeat the exercise in Problem 2.7 for the 4s and...Ch. 2 - Repeat the exercise in Problem 2.7 for the 5s and...Ch. 2 - The 4fz(x2y2) orbital has the angular function...Ch. 2 - Prob. 2.13PCh. 2 - The label for an fz2 orbital, like that for a dz2...Ch. 2 - a. Determine the possible values for the l and ml...Ch. 2 - a. What are the values of quantum numbers I and n...Ch. 2 - a. At most, how many electrons in an atom can have...Ch. 2 - Determine the Coulombic and exchange energies for...Ch. 2 - Prob. 2.19PCh. 2 - Prob. 2.20PCh. 2 - What states are possible for a d3 configuration?...Ch. 2 - Provide explanations of the following phenomena:...Ch. 2 - Give electron configurations for the following:...Ch. 2 - Predict the electron configurations of the...Ch. 2 - Radial probability plots shed insight on issues of...Ch. 2 - Briefly explain the following on the basis of...Ch. 2 - Briefly explain the following on the basis of...Ch. 2 - a. Which 2+ ion has two 3d electrons? Which has...Ch. 2 - A sample calculation in this chapter showed that,...Ch. 2 - Ionization energies should depend on the effective...Ch. 2 - Prepare a diagram such as the one in Figure (a)...Ch. 2 - Why are the ionization energies of the alkali...Ch. 2 - The second ionization of carbon (C+C2++e) and the...Ch. 2 - Prob. 2.35PCh. 2 - Prob. 2.36PCh. 2 - The second ionization energy involves removing an...Ch. 2 - Prob. 2.38PCh. 2 - On the basis of electron configurations, explain...Ch. 2 - a. The graph of ionization energy versus atomic...Ch. 2 - The second ionization energy of He ¡s almost...Ch. 2 - The size of the transition-metal atoms decreases...Ch. 2 - Predict the largest and smallest radius in each...Ch. 2 - Select the best choice, and briefly indicate the...Ch. 2 - Select the best choice, and briefly indicate the...Ch. 2 - There are a number of Web sites that display...Ch. 2 - Prob. 2.47P
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- Which of the following elements is most likely to form an oxide with the formula MO3: Zr, Nb, or Mo?arrow_forwardA) Which of the halogen elements has the highest density in its standard state? B) Which of the elements of the third period should have the highest 2nd ionization energy? C) For which of Al, Si or P is the absolute value of the Electron Affinity greatest? D) Which of the ions Mg2+, Sr2+, Ca2+, Be2+, Ba2+, or Ra2+ is the smallest? E) For the elements: X = Br, I, Cl, or H, which has the the smallest average X-C bond energy?arrow_forwardExplains the writing method that allows you to complete the configuration phosphorus electron (Z = 15). In your answer, highlight the following principles and concepts. The configuration written by layer and sublayer (1s 2, 2s 2, etc.) The use of quantum cells The Pauli principle of exclusion Hund's rulearrow_forward
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