(a)
Interpretation:
The empirical relationship between ϕ and T should be determined.
Concept introduction:
The temperature of a system is controlled by passing cooling water through a jacket that covers the system. The system temperature (T) and the water flow rate (ϕ) through the cooling jacket is measured.
In addition, it is given that data are taken for T versus ϕ. Plots of T versus ϕ on rectangular and semi-log coordinates are distinctly curved. The possible empirical functions such as T = a ϕ + b and T = a e bϕ (a and b are constants) are not taken into consideration by the author.
(b)
Interpretation:
Using the derive equation, the cooling water flow rates needed to maintain the process unit temperature at 85°C, 175°C and 290°C should be calculated.
Concept introduction:
The temperature of a system is controlled by passing cooling water through a jacket that covers the system. The system temperature (T) and the water flow rate (ϕ) through the cooling jacket are measured and give by,
The relationship
Where T = system temperature and ϕ = water flow rate through the cooling jacket
(c)
Interpretation:
The most confidence estimate, and least confidence estimate should be explained from the three estimates in part (b).
Concept introduction:
The temperature of a system is controlled by passing cooling water through a jacket that covers the system. The system temperature (T) and the water flow rate (ϕ) through the cooling jacket are measured and give by,
The relationship is
Where T = system temperature and ϕ = water flow rate through the cooling jacket
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Chapter 2 Solutions
ELEMENTARY PRINCIPLES OF CHEM. PROCESS.
- 05) Determine Assume the soil coefficient (log Koc). factor teem in your molecular structure is given as по Collection The followe : Calculations. Bekow CI Given, log Koc = ос NH2 0.53' x + 0.62 + Σ n; Pj, Where X is the first order molecular connectivity n; is the number of groups of type 'j molecule and Pj Is Collection factor in Index the for each group. (6 marks) [Last question Numericalarrow_forward150 kmol of an aqueous phosphoric acid solution contains S mol percent H3P04. The solution is concentrated by adding pure phosphoric acid at a rate of 20L per minute. Write a differential mole balance on phosphoric acid and provide an initial condition. Solve the balance to abtain an expression vdor np(t) . Use the result to derive an expression far xp(t), the mole fraction of phosphoric acid in the solution. How long will it take to concentrate the solution to IS percent H3P04 ?arrow_forwardL-Serine is an amino acid important for its roles in synthesizing other amino acids and for its use in intravenous feeding solutions. It is often synthesized commercially by fermentation, and recovered by subjecting the fermentation broth to several processing steps and then crystallizing the serine from an aqueous solution. The solubilities of L-serine (L-Ser) in water have been measured at several temperatures, producing the following data:5T(K) 283.4 285.9 289.3 299.1 316.0 317.8 322.9 327.1x(mole fraction L-Ser) 0.0400 0.0426 0.0523 0.0702 0.1091 0.1144 0.1181 0.1248One of the ways such data can be represented is with the van’t Hoff equation: ln x =( a=T b).Graph the data so that the resulting plot is linear. Estimate a and b and give their units.arrow_forward
- A 150 pounds of (NaCI) is dissolved in the solution in container A and 100 pounds of (NaCI) is dissolved in the solution in container B. The system is closed in that the well-stirred liquid is pumped only between the containers, as shown in Fig. (A)Calculate the number of pounds mixture Of salt at time t in 3 gal/min containers A and B. (B) what is the relation between the variables x1(t) and x2(t) that holds at time t. Explain why this relation makes intuitive sense. Use this relation to help find 100 gal 100 gal mixture the amount of salt in tank B at t = 15 min. 2 gal/minarrow_forward(a) Water supplies are often treated with chlorine as one of the processing steps in treating wastewater. Estimate the liquid diffusion coefficient of chlorine in an infinitely dilute solution of water at 289 K using the Wilke-Chang equation. (b) Estimate the liquid diffusivity of the following solutes that are transferred through dilute solutions: (i) oxygen in water at 18ºC; (ii) CO2 in water at 25ºC.arrow_forwardThe highest building in Montreal is the ‘1 square building’, with a height of 203m.The atmospheric pressure in the streets of Montreal is P1 = 9.9 x 104Pa.Suppose air density is constant : ρair= 1,2 kg/m3 and g = 9.8 m/s2. Suppose the rooftop temperature to be T = 298K, and the air composition is 100%N2 molecules. The collision cross-section of N2 molecules is 0.43 nm2.*f. Find the collision frequency. Is it in the order of magnitude that you wereexpecting?arrow_forward
- 4. A new method for the determination of mercury in fish was tested against a N.I.S.T. standard to determine if there was any bias (determinate error) in the new technique. The N.I.S.T. standard fish sample was certified to contain 13.55 ppm Hg. The results of six analyses by the new method gave a mean value of 14.15 ppm and s.d. = 0.42 ppm. Does the new method give accurate results at the 95% confidence level?arrow_forwardA gas mixture at 300K and 1 bar analyzing by volume 20% N2 and 80% CH4 is subjected to liquefaction at the rate of 1500 kg/hr. It is found that only 30% (weight) of the entering gas is liquefied and the concentration of N2 in the liquid is 60% by weight. The unliquefied gas leaves the unit at 273K and 1 bar. Determine (a) the volume of the unliquefied gas, m3/hr (b) the composition of the gas leaving expressed as volume %.arrow_forwardEXAMPLE. Compute the atmospheric pressure on a day when the height of the barometer is 76.0 cm. The height of the mercury column, from Eq. (16-6), depends on p and g as well as on the atmospheric pressure. Hence both the density of mercury and the local acceleration of gravity must be known. The density varies with the tem- perature, and g with the latitude and elevation above sea level. barometers are provided with a thermometer and with a table or chart from which corrections for temperature and elevation can be found. g = 980 cm/sec2 and p = 13.6 gm/cm³, All accurate If we assumearrow_forward
- Te (K) (bar)| (Pa (m/kmol)²) | (m³/kmol) 190.6| 46 305.3 49 |369.5 42.5 Pe a b Natural gas is produced in a gas field outside of the City of Grande Prairie and is delivered through a pipeline to a sales point. At the sales point, the pressure in the pipeline is 5 MPa Propane and the temperature is 20°C. The natural gas is composed of 85 mol% methane, 10 mol% ethane and 5 mol% propane. Selected properties of these components have been provided in the table above. Using the information provided, answer the questions below. Component Methane Ethane 5.56x105 0.0638 8.78x10 0.0845 m3 m3 (c) Calculate the values of a (in Pa· ) and b (in ) for the mixture. kmol, kmol,arrow_forwardb) A gaseous mixture contain 32.9 mol % He, 40.7 mol % N2 and 26.4 mol % Ar. Determine the composition of this mixture on a mass basis based on the molecular weight given: MW (He) = 4.003 , MW (N2) = 28.02, MW(Ar) = 39.95 %3Darrow_forwardA drug is infused continuously intravenously (IV) for treatment of a particular disease. The volume of the body fluid V = 16 liters. The drug is excreted (removed) through the kidneys at rate ke, proportional to the concentration of the drug in the body fluids. The drug is ineffective and not used by the body if its concentration is below Cmin and becomes poisonous if the concentration goes over Cmax. It is metabolized at a rate km as the concentration is 2Cmin- Let the parameter values Cmin = 4 mg/I, Cmax =40 mg/I, ke = 0.2/hr and km = 0.3/hr. a. How much is the maximum possible rate of infusion of the drug? b. How long the drug would continue to be effective if the infusion has been stopped as the concentration reached at the maximum level?arrow_forward
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