Concept explainers
Interpretation:
The data for three compounds and their percent by mass of the elements
The possible thing to know about the empirical formulas for these three compounds has to be determined.
Explanation of Solution
The three compounds have different formulas. The first of these has a larger number of
Masses shows that these three compounds have the same proportion of
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Chapter 2 Solutions
Chemistry: The Molecular Science
- Consider the following data for three binary compounds of hydrogen and nitrogen: %H (by Mass) %N (by Mass) I 17.75 82.25 II 12.58 87.42 III 2.34 97.66 When 1.00 L of each gaseous compound is decomposed to its elements, the following volumes of H2(g) and N2(g) are obtained: H2(L) N2(L) I 1.50 0.50 II 2.00 1.00 III 0.50 1.50 Use these data to determine the molecular formulas of compounds I, II, and III and to determine the relative values for the atomic masses of hydrogen and nitrogen.arrow_forwardGallium arsenide, GaAs, has gained widespread use in semiconductor devices that convert light and electrical signals in fiber-optic communications systems. Gallium consists of 60.% 69Ga and 40.% 71Ga. Arsenic has only one naturally occurring isotope, 75As. Gallium arsenide is a polymeric material, but its mass spectrum shows fragments with the formulas GaAs and Ga2As2. What would the distribution of peaks look like for these two fragments?arrow_forwardThe element bromine is Br2, so the mass of a Br2 molecule is the sum of the mass of its two atoms. Bromine has two isotopes. The mass spectrum of Br2 produces three peaks with relative masses of 157.836, 159.834, and 161.832, and relative heights of 6.337, 12.499. and 6.164, respectively. (a) What isotopes of bromine are present in each of the three peaks? (b) What is the mass of each bromine isotope? (c) What is the average atomic mass of bromine? (d) What is the abundance of each of the two bromine isotopes?arrow_forward
- The mass spectrum of phosphoryl chloride. POF3, is illustrated here. (a) Identify the cation fragment at a m/Z ratio of 85. (b) Identify the cation fragment at a m/Z ratio of 69. (c) Which two peaks in the mass spectrum provide evidence that the oxygen atom is connected to the phosphorus atom and is not connected to any of the three fluorine atoms?arrow_forwardBoron consists of two isotopes, 10B and 11B. Chlorine also has two isotopes, 35Cl and 37Cl. Consider the mass spectrum of BC13. How many peaks would be present, and what approximate mass would each peak correspond to in the BCl3 mass spectrum?arrow_forwardThe mass spectrum of bromine (Br2) consists of three peaks with the following characteristics: Mass (u) Relative Size 157.84 0.2534 159.84 0.5000 161.84 0.2466 How do you interpret these data?arrow_forward
- 3.116 The simplest approximate chemical formula for the human body could be written as C728H4850O1970N104Ca24P16K4S4Na3Cl2Mg. Based on this formula, describe how you would rank by mass the ten most abundant elements in the human body.arrow_forwardThe density of a mixture of gases may be calculated by summing the products of the density of each gas and the fractional volume of space occupied by that gas. (Note the similarity to the calculation of the molar mass of an element from the isotopic masses and fractional abundances.) Assume dry air with CO2 removed is 20.96% (by volume) oxygen. 78.11% nitrogen, and 0.930% argon. Determine the density of argon.arrow_forward
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