Concept explainers
Draw the product when each compound is treated with either
a. b. c.
(a)
Interpretation: The product formed by the treatment of given compound with either
Concept introduction: Organometallic reagents like
Answer to Problem 20.34P
The product formed by the treatment of given compound with
Figure 1
Explanation of Solution
The given reagents are organocuprate
The product formed by the reaction of
Figure 2
The product formed by the reaction of
Figure 3
The product formed by the treatment of given compound with
(b)
Interpretation: The product formed by the treatment of given compound with either
Concept introduction: Organometallic reagents like
Answer to Problem 20.34P
The product formed by the treatment of given compound with
Figure 4
Explanation of Solution
The given reagents are organocuprate
The product formed by the reaction of
Figure 5
The product formed by the reaction of
Figure 6
The product formed by the treatment of given compound with
(c)
Interpretation: The product formed by the treatment of given compound with either
Concept introduction: Organometallic reagents like
Answer to Problem 20.34P
The product formed by the treatment of given compound with
Figure 7
Explanation of Solution
The given reagents are organocuprate
The product formed by the reaction of
Figure 8
The product formed by the reaction of
Figure 9
The product formed by the treatment of given compound with
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Chapter 20 Solutions
ORGANIC CHEM W/CNCT+SOLUTION MANUAL >BI<
- (a) Give the IUPAC name for A and B. (b) Draw the product formed when A or B is treated with each reagent: [1] NaBH4, CH3OH; [2] CH3MgBr, then H2O; [3] Ph3P = CHOCH3; [4] CH3CH2CH2NH2, mild acid; [5] HOCH2CH2CH2OH, H+.arrow_forwardDraw the products formed when A or B is treated with each reagent. In some cases, no reaction occurs. [1] C6H5Li (excess); [2] H2Oarrow_forward(a) Give an acceptable name for each compound, (b) Draw the organic products formed when A or B is treated with each reagent: [1] H3O+; [2] −OH, H2O; [3] CH3CH2CH2MgBr (excess), then H2O; [4] LiAlH4, then H2O.arrow_forward
- Draw the missing starting material. Reagent 1 is benzene and AlCl3. Reagent B is Zn(Hg) and HCl.arrow_forward(a) Give an acceptable name for compound A. (b) Draw the organic products formed when A is treated with each reagent: [1] H3O+; [2] −OH, H2O; [3] CH3CH2CH2MgBr (excess), then H2O; [4] LiAlH4, then H2O.arrow_forwardwhich reagents complete the reaction?arrow_forward
- Devise a synthesis of each substituted cyclopropane. Use acetylene (HC=CH) as a starting material in part (a) and cyclohexanone as a starting material in part (b). You may use any other organic compounds and any needed reagents.arrow_forwardDraw the products formed when phenol(C6H5OH) is treated with each reagent. Give an explanation. c. CH3CH2Cl, AlCl3 l. product in (c), then KMnO4arrow_forwardEthers are oxidized with O2 to form hydroperoxides that decompose violently when heated. Draw a stepwise mechanism for this reaction.arrow_forward
- Draw the product formed when (CH3)2CHOH is treated with following reagent. HBrarrow_forwardWhat product results from the SN2 reaction between (R)-2-chloropentane and hydroxide? A. (R)-2-pentanol B. (S)-2-pentanol C. Both A and B D. 1-pentanolarrow_forwardDraw the product when each compound is treated with either (CH3)2CuLi, followed by H2O, or HC≡CLi, followed by H2O.arrow_forward
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