(a)
Interpretation:
The complete and detailed mechanism for the given reaction is to be drawn, and the overall product of the reaction is to be predicted.
Concept introduction:
This is saponifiaction reaction. A
The irreversible deprotonation in Step 3 makes the overall saponification reaction irreversible. The initial carboxylic acid is produced reversibly, but it is continually removed via Step 3, which helps drive the reaction to completion.
(b)
Interpretation:
The complete and detailed mechanism for the given reaction is to be drawn, and the overall product of the reaction is to be predicted.
Concept introduction:
This is saponifiaction reaction. A carboxylic acid is produced when an ester undergoes saponification, followed by acid workup. Steps 1 and 2 are identical to the nucleophilic addition and elimination steps. Step 3 is the rapid, irreversible deprotonation of the newly formed carboxylic acid. Finally, the proton is replenished by adding a strong acid.
The irreversible deprotonation in Step 3 makes the overall saponification reaction irreversible. The initial carboxylic acid is produced reversibly, but it is continually removed via Step 3, which helps drive the reaction to completion.
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Chapter 20 Solutions
ORGANIC CHEMISTRY:PRINCIPLES...(PB)
- Predict the major product of each of the reactions shown here and provide the complete, detailed mechanism.arrow_forwardDraw the complete, detailed mechanism and the products for each of the following reactions.arrow_forwardDraw a complete, detailed mechanism for the reaction shown here.arrow_forward
- Predict the major product of each of the following reactions and provide the complete, detailed mechanismarrow_forwardPlease draw the complete, detailed mechanism for each of thesearrow_forwardDraw a complete, detailed mechanism for the following reaction. A key intermediate is provided.arrow_forward
- Draw the complete, detailed mechanism for the following reaction, and predict the major product. NaCI MeOHarrow_forwardProvide the full mechanism and major products for each of the following reactions.arrow_forwardOne way to synthesize diethyl ether is to heat ethanol in the presence of a strong acid, as shown here. Draw a complete, detailed mechanism for this reaction.arrow_forward
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