Quantitative Chemical Analysis
Quantitative Chemical Analysis
9th Edition
ISBN: 9781464135385
Author: Daniel C. Harris
Publisher: W. H. Freeman
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Question
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Chapter 20, Problem 20.AE

(a)

Interpretation Introduction

Interpretation:

The wavelength of two spectral lines has to be distinguished.

Concept introduction:

The wavelength of two spectral lines calculated via below the formula

λΔλwhereλ=wavelengthof spectral line

(a)

Expert Solution
Check Mark

Answer to Problem 20.AE

The wavelength of two spectral lines will be resolved.

Explanation of Solution

Given

λ=10.00μmand10.01μm

thevalueofλ=10.00μmandΔλ0.01μmλΔλ=10.000.01=103

The given resolution is 104 so the observed and given both resolution almost equal so the lines will be resolved.

(b)

Interpretation Introduction

Interpretation:

The resolution close to wavenumber has to be has to be calculated.

Concept introduction:

The resolution close to wavenumber calculated via below the formula

λ=1υ˜whereλ=wavelengthof spectral lineυ˜=wavenumber

(b)

Expert Solution
Check Mark

Answer to Problem 20.AE

The resolution close to wavenumber both deference is0.1cm-1

Explanation of Solution

The given resolution is 104

λ=1υ˜

λ=1(1000cm-1)(10-4cm/μm)=10μmΔλ=λ104=10-3μm

10.001μmcoundbe resolvedfrom100μm

10.001μm=1000cm-110.001μm=999.9cm-1}thedifferenceis0.1cm-1

(c)

Interpretation Introduction

Interpretation:

The resolution of first and tenth-order has to be calculated.

(c)

Expert Solution
Check Mark

Answer to Problem 20.AE

The resolution of first and tenth-order is 12500forn=1 and 125000forn=10

Explanation of Solution

Given

5.0cm×2500line/cm=12500lines

Resolution:

=1.1250012500forn=1=10.12500125000forn=10

(d)

Interpretation Introduction

Interpretation:

The angular dispersion has to be fined.

Concept introduction:

Dispersion: It measure the ability to separate wavelengths differing by Δλ through the difference in angle Δϕ

Dispersion of grating:

ΔϕΔλ=ndcosϕn=isthediffractionorder

(d)

Expert Solution
Check Mark

Answer to Problem 20.AE

The angular dispersion is 0.3o

Explanation of Solution

ΔϕΔλ=ndcosϕ

2(1mm250)cos30o

577radiansmm=0.577radiansμmconvertradianstodegreesradiansπ×180

ΔfΔλ=33.1degrees/μm

Two wavelengths are

1000cm-1=10μmand1001cm-1Δλ=0.01μm

Δλ=0.577radiansmm×0.01μm=6×10-3radian=0.3o

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