Concept explainers
Interpretation:
The question asks one to write the equations corresponding to the oxidation of a primary alcohol and a secondary alcohol. Also one needs to specify the structure of each alcohol and the principal products of oxidation.
Concept Introduction:
Monohydric alcohols can be categorized into three types as primary, secondary and tertiary alcohols.
AS shown above in primary alcohols carbon with the −OH group is bonded to only one carbon whereas in secondary alcohols, carbon with the −OH group is bonded to two other carbon atoms. In tertiary alcohols(not shown here), carbon with the −OH group is bonded to three other carbon atoms.
In the alcohols the −OH bond is polarized placing partially negative charge on O atom while placing a partially positive charge on the alkyl carbon atom of the R-OH bond. Hence due to the inter molecular hydrogen bonds formed between alcohol molecules, their boiling points have higher values compared to the
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Chapter 20 Solutions
EBK INTRODUCTORY CHEMISTRY
- Introductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage LearningIntroductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage LearningWorld of Chemistry, 3rd editionChemistryISBN:9781133109655Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCostePublisher:Brooks / Cole / Cengage Learning
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage LearningChemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
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