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Chemistry: An Atoms First Approach

2nd Edition
Steven S. Zumdahl + 1 other
Publisher: Cengage Learning
ISBN: 9781305079243

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BuyFindarrow_forward

Chemistry: An Atoms First Approach

2nd Edition
Steven S. Zumdahl + 1 other
Publisher: Cengage Learning
ISBN: 9781305079243
Chapter 20, Problem 82AE
Textbook Problem
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For the process

Co ( NH 3 ) 5 Cl 2 + + Cl CO ( NH 3 ) 4 Cl 2 + + NH 3

what would be the expected ratio of cis to trans isomers in the product?

Interpretation Introduction

Interpretation: The expected ratio of cis to trans isomers in the product of given process is to be stated.

Concept introduction: The compounds which have similar chemical formula but different structures, i.e., the atoms are in a different spatial arrangement, they are known as structural isomers. Cis and Trans isomers are also structural or geometrical isomers.

To determine: The expected ratio of cis to trans isomers in the product of given process.

Explanation of Solution

Explanation

The product of the given reaction is Co(NH3)Cl2+ .

Its cis isomer is,

Figure 1

Its trans isomer is,

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Chapter 20 Solutions

Chemistry: An Atoms First Approach
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Ch. 20 - You isolate a compound with the formula PtCl4 ...Ch. 20 - Both Ni(NH3)42+ and Ni(SCN)42 have four ligands....Ch. 20 - Which is more likely to be paramagnetic, Fe(CN)64...Ch. 20 - A metal ion in a high-spin octahedral complex has...Ch. 20 - What is the lanthanide contraction? 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