Organic Chemistry
Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
Question
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Chapter 20.10, Problem 33CC

(a)

Interpretation Introduction

Interpretation:

The major product transformation should be drawn and identified for the given corresponding starting molecules by using its structures.

Concept introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Grignard Reaction: This is a organometallic reaction in different alkyl, aryl-magnesium halides add to a carbonyl group in an aldehyde and ketone. This reaction is an important for the conversion of carbon-carbon single (CC) bond. Moreover the addition of a reagent to an aster, lactone gives a tertiary alcohol in which will alkyl groups are the same and the addition of a Grignard reagent to a nitrile produces an unsymmetrical ketone.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π-bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

(b)

Interpretation Introduction

Interpretation:

The major product transformation should be drawn and identified for the given corresponding starting molecules by using its structures.

Concept introduction:

Concept introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Grignard Reaction: This is a organometallic reaction in different alkyl, aryl-magnesium halides add to a carbonyl group in an aldehyde and ketone. This reaction is an important for the conversion of carbon-carbon single (CC) bond. Moreover the addition of a reagent to an aster, lactone gives a tertiary alcohol in which will alkyl groups are the same and the addition of a Grignard reagent to a nitrile produces an unsymmetrical ketone.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π-bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

(c)

Interpretation Introduction

Interpretation:

The major product transformation should be drawn and identified for the given corresponding starting molecules by using its structures.

Concept introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Grignard Reaction: This is a organometallic reaction in different alkyl, aryl-magnesium halides add to a carbonyl group in an aldehyde and ketone. This reaction is an important for the conversion of carbon-carbon single (CC) bond. Moreover the addition of a reagent to an aster, lactone gives a tertiary alcohol in which will alkyl groups are the same and the addition of a Grignard reagent to a nitrile produces an unsymmetrical ketone.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π-bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

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Chapter 20 Solutions

Organic Chemistry

Ch. 20.5 - Prob. 12CCCh. 20.5 - Prob. 13CCCh. 20.5 - Prob. 14CCCh. 20.6 - Prob. 3LTSCh. 20.6 - Prob. 15PTSCh. 20.6 - Prob. 16ATSCh. 20.6 - Prob. 17ATSCh. 20.6 - Prob. 18ATSCh. 20.6 - Prob. 19CCCh. 20.6 - Prob. 20CCCh. 20.6 - Prob. 4LTSCh. 20.6 - Prob. 21PTSCh. 20.6 - Prob. 22ATSCh. 20.6 - Prob. 23ATSCh. 20.6 - Prob. 24ATSCh. 20.7 - Prob. 5LTSCh. 20.7 - Prob. 26PTSCh. 20.7 - Prob. 27ATSCh. 20.7 - Prob. 28CCCh. 20.8 - Prob. 29CCCh. 20.8 - Prob. 30CCCh. 20.9 - Prob. 31CCCh. 20.9 - Prob. 32CCCh. 20.10 - Prob. 33CCCh. 20.10 - Prob. 34CCCh. 20.10 - Prob. 35CCCh. 20.10 - Prob. 36CCCh. 20.10 - Prob. 6LTSCh. 20.10 - Prob. 37PTSCh. 20.10 - Prob. 38ATSCh. 20.10 - Prob. 39ATSCh. 20.11 - Prob. 40CCCh. 20.12 - Prob. 7LTSCh. 20.12 - Prob. 41PTSCh. 20.12 - Prob. 42PTSCh. 20.13 - Prob. 43CCCh. 20 - Prob. 44PPCh. 20 - Prob. 45PPCh. 20 - Prob. 46PPCh. 20 - Prob. 47PPCh. 20 - Prob. 48PPCh. 20 - Prob. 49PPCh. 20 - Prob. 50PPCh. 20 - Prob. 51PPCh. 20 - Prob. 52PPCh. 20 - Prob. 53PPCh. 20 - Prob. 54PPCh. 20 - Prob. 55PPCh. 20 - Prob. 56PPCh. 20 - Prob. 57PPCh. 20 - Prob. 58PPCh. 20 - Prob. 59PPCh. 20 - Prob. 60PPCh. 20 - Prob. 61PPCh. 20 - Prob. 62PPCh. 20 - Prob. 63PPCh. 20 - Prob. 64PPCh. 20 - Prob. 65PPCh. 20 - Prob. 66PPCh. 20 - Prob. 67PPCh. 20 - Prob. 68PPCh. 20 - Prob. 69PPCh. 20 - Prob. 70PPCh. 20 - Prob. 71PPCh. 20 - Prob. 72PPCh. 20 - Prob. 73PPCh. 20 - Prob. 74PPCh. 20 - Prob. 75PPCh. 20 - Prob. 76IPCh. 20 - Prob. 77IPCh. 20 - Prob. 78IPCh. 20 - Prob. 79IPCh. 20 - Prob. 80IPCh. 20 - Prob. 81IPCh. 20 - Prob. 82IPCh. 20 - Prob. 83IPCh. 20 - Prob. 84IPCh. 20 - Prob. 85IPCh. 20 - Prob. 86IP
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