Chemistry
4th Edition
ISBN: 9780078021527
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 21, Problem 11QP
The highly reactive OH radical (a species with an unpaired electron) is believed to be involved in some atmospheric processes. Table 8.6 lists the bond enthalpy for the oxygen-to-hydrogen bond in OH as 460 kJ/mol. What is the longest wavelength (in nm) of radiation that can bring about the following reaction?
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(a) When chlorine atoms react with atmospheric ozone,what are the products of the reaction? (b) Based on averagebond enthalpies, would you expect a photon capable ofdissociating a C—Cl bond to have sufficient energy to dissociatea C—Br bond? (c) Would you expect the substanceCFBr3 to accelerate depletion of the ozone layer?
It is often said that water vapour amplifies the Earth’s greenhouse effect. Indicate one way that an increased atmospheric concentration water vapour can increase the greenhouse effect and one way that it can decrease the greenhouse effect.
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Chapter 21 Solutions
Chemistry
Ch. 21.1 - Practice Problem ATTEMPT Calculate the wavelength...Ch. 21.1 - Practice Problem BUILD Which of the following...Ch. 21.1 - Prob. 1PPCCh. 21.1 - Prob. 1CPCh. 21.1 - Prob. 2CPCh. 21.2 - Practice Problem ATTEMPT which of the following is...Ch. 21.2 - Practice Problem BUILD Both O 2 and O 3 exhibit...Ch. 21.2 - Prob. 1PPCCh. 21.2 - 21.2.1 What maximum wavelength (in nm) of fight is...Ch. 21.2 - What process gives rise to the aurora borealis and...
Ch. 21.3 - Prob. 1PPACh. 21.3 - Practice Problem BUILD How long will it take for...Ch. 21.3 - Prob. 1PPCCh. 21.8 - Prob. 1CPCh. 21.8 - Prob. 2CPCh. 21 - Prob. 1QPCh. 21 - Prob. 2QPCh. 21 - Prob. 3QPCh. 21 - Prob. 4QPCh. 21 - Referring to Table 21.1, calculate the mole...Ch. 21 - Prob. 6QPCh. 21 - Prob. 7QPCh. 21 - Calculate the mass (in kg) of nitrogen, oxygen,...Ch. 21 - 21.9 What process gives rise to the aurora...Ch. 21 - Prob. 10QPCh. 21 - The highly reactive OH radical (a species with an...Ch. 21 - The green color observed in the aurora borealis is...Ch. 21 - Prob. 13QPCh. 21 - Prob. 14QPCh. 21 - Prob. 15QPCh. 21 - Prob. 16QPCh. 21 - What causes the polar ozone holes?Ch. 21 - How do volcanic eruptions contribute to ozone...Ch. 21 - Prob. 19QPCh. 21 - Discuss the effectiveness of some of the CFC...Ch. 21 - Prob. 21QPCh. 21 - Prob. 22QPCh. 21 - Prob. 23QPCh. 21 - Prob. 24QPCh. 21 - Prob. 25QPCh. 21 - Prob. 26QPCh. 21 - Prob. 27QPCh. 21 - Prob. 28QPCh. 21 - Prob. 29QPCh. 21 - Prob. 30QPCh. 21 - Prob. 31QPCh. 21 - Prob. 32QPCh. 21 - Describe three human activities that generate...Ch. 21 - Prob. 34QPCh. 21 - Prob. 35QPCh. 21 - Prob. 36QPCh. 21 - What effects do CFCs and their substitutes have on...Ch. 21 - Why are CFCs more effective greenhouse gases than...Ch. 21 - Prob. 39QPCh. 21 - Calcium oxide or quicklime ( CaO ) is used in...Ch. 21 - Prob. 41QPCh. 21 - 21.42 List three detrimental effects of acid...Ch. 21 - 21.43 Briefly discuss two industrial processes...Ch. 21 - Discuss ways to curb acid rain.Ch. 21 - Prob. 45QPCh. 21 - Prob. 46QPCh. 21 - Prob. 47QPCh. 21 - Identify the gas that is responsible for the brown...Ch. 21 - 21.49 The safety limits of ozone and carbon...Ch. 21 - Prob. 50QPCh. 21 - Prob. 51QPCh. 21 - 21.52 The gas-phase decomposition of peroxyacetyl...Ch. 21 - 21.53 On a smoggy day in a certain city. the ozone...Ch. 21 - Prob. 54QPCh. 21 - What is the best way to deal with indoor...Ch. 21 - Why is it dangerous to idle a car's engine in a...Ch. 21 - Prob. 57QPCh. 21 - Prob. 58QPCh. 21 - Prob. 59QPCh. 21 - Prob. 60APCh. 21 - Prob. 61APCh. 21 - Prob. 62APCh. 21 - Prob. 63APCh. 21 - Prob. 64APCh. 21 - 21.65 How are past temperatures determined from...Ch. 21 - The balance between SO 2 and SO 3 is important in...Ch. 21 - Prob. 67APCh. 21 - 21.68 A glass of water initially at pH 7.0 is...Ch. 21 - Prob. 69APCh. 21 - 21.70 Instead of monitoring carbon dioxide,...Ch. 21 - Describe the removal of SO 2 by CaO (to form CaSO...Ch. 21 - 21.72 Which of the following settings is the most...Ch. 21 - Prob. 73APCh. 21 - Peroxyacetyl nitrate (PAN) undergoes thermal...Ch. 21 - Prob. 75APCh. 21 - Prob. 76APCh. 21 - 21.77 The carbon dioxide level in the atmosphere...Ch. 21 - Prob. 78APCh. 21 - Prob. 79APCh. 21 - 21.80 A person was found dead of carbon monoxide...Ch. 21 - Prob. 81APCh. 21 - Prob. 82APCh. 21 - The molar heat capacity of a diatomic molecule is...Ch. 21 - Prob. 84APCh. 21 - Prob. 85APCh. 21 - Prob. 86APCh. 21 - Prob. 1SEPPCh. 21 - Prob. 2SEPPCh. 21 - Prob. 3SEPPCh. 21 - Prob. 4SEPP
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- Chlorine atoms contribute to the destruction of the Earths ozone layer by the following sequence of reactions: Cl + O3 ClO + O2 ClO + O Cl + O2 where the O atoms in the second step come from the decomposition of ozone by sunlight: O3(g) O(g) + O2(g) What is the net equation on summing these three equations? Why does this lead to ozone loss in the stratosphere? What is the role played by Cl in this sequence of reactions? What name is given to species such as ClO?arrow_forwardThe tropospheric processes discussed in this chapter cannot be considered as independent reactions. Discuss the relationship between the production of nitrogen oxide species and the formation of ‘acid rain’ and the role played by carbon monoxide, methane, and the hydroxyl radical.arrow_forwardWhat is the biological importance of stratospheric ozone? Explain.arrow_forward
- 11.7. What is a greenhouse gas? Give the chemical formulas of two compounds that function as greenhouse gasesarrow_forwardExplain the relevance of the 1987 Montreal Protocol and its 2016 Kigali Amendment on regulating ozone depletion.arrow_forwardDiscuss the causes and impacts of enhanced greenhouse effect.arrow_forward
- How does the ground temperature in sunlight with CO2 compare with ground temperature in sunlight without CO2?arrow_forwardThe average length of an O–O single bond is 132 pm. The average length of an O–O double bond is 121 pm. What do you predict the O–O bond lengths will be in ozone? Will they all be the same? Explain your predictions.arrow_forwardChapter #3, Question #13: Consider the following data for total atmospheric column ozone measurements (as DU) at three locations around the Earth, obtained using the TOMS in 2001. January 15 april 15 july 15 october 15 Tierra del fuego (Chilie, argentina) 323 261 339 206 Nairobi (Kenya) 234 273 266 (Aug. 15) 266 Kiev (Ukraine) 321 420 314 273 Assume that these are typical of values that might be obtained in any other year, and discuss the trends as you move down the columns and along the rows, in terms of your knowledge of stratospheric ozone behavior.arrow_forward
- 4.) The dissociation energy of a carbon-bromine bond is typically about 276 KJ/mol. What is the maximum wavelength of photons that cause C---- Br bonds dissociation? and which kind of electromagnetic radiation--ultraviolet, visible, or infrared--does the wavelength you calculated correspond to? Group of answer choices A) 435 nm; Blue visible light B) 570 nm; Green/yellow visible light C) 7.2 x 10-31 m; gamma rays D) 435 nm; Red visible lightarrow_forwardA proposed two-step mechanism for the destruction of ozone in the upper atmosphere is a. What is the overall balanced equation for the ozone destruction reaction? b. Which species is a catalyst? c. Which species is an intermediate? d. What is the rate law derived from this mechanism if the first step in the mechanism is slow and the second step is fast? e. One of the concerns about the use of Freons is that they will migrate to the upper atmosphere, where chlorine atoms can be generated by the reaction Chlorine atoms also can act as a catalyst for the destruction of ozone. The first step of a proposed mechanism for chlorine-catalyzed ozone destruction is Cl (g) + O3 (g) → ClO (g) + O2 (g) Slow Assuming a two-step mechanism, propose the second step in the mechanism and give the overall balanced equation.arrow_forwardSO2 is not actually a significant greenhouse gas, while SF6 is. Explain this difference by commenting on their expected behaviour in the atmosphere. (What will happen or not happen to each gas after it is emitted?)arrow_forward
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