Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 21, Problem 48E
The foul odor of rancid butter is caused by butyric acid, CH3CH2CH2CO2H.
(a) Draw the Lewis structure and determine the oxidation number and hybridization for each carbon atom in the molecule.
(b) The esters formed from butyric acid are pleasant-smelling compounds found in fruits and used in perfumes. Draw the Lewis structure for the ester formed from the reaction of butyric acid with 2-propanol.
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The foul odor of rancid butter is caused by butyric acid, CH3CH2CH2CO2H.(a) Draw the Lewis structure and determine the oxidation number and hybridization for each carbon atom in the molecule.(b) The esters formed from butyric acid are pleasant-smelling compounds found in fruits and used in perfumes. Draw the Lewis structure for the ester formed from the reaction of butyric acid with 2-propanol.
Draw a compound with the molecular formula C7H12O2 that contains an ester
Draw the condensed structure of the compounds formedby condensation reactions between (a) benzoic acid andethanol, (b) ethanoic acid and methylamine, (c) acetic acidand phenol. Name the compound in each case.
Chapter 21 Solutions
Chemistry Atoms First2e
Ch. 21 - Write the chemical formula and Lewis structure of...Ch. 21 - What is the difference between the hybridization...Ch. 21 - On a microscopic level, how does the reaction of...Ch. 21 - On a microscopic level, how does the reaction of...Ch. 21 - Explain why unbranched alkenes can form geometric...Ch. 21 - Explain why these two molecules are not isomers:Ch. 21 - Explain why these two molecules are not isomers:Ch. 21 - How does the carbon-atom hybridization change when...Ch. 21 - Write the Lewis structure and molecular formula...Ch. 21 - Write the chemical formula, condensed formula, and...
Ch. 21 - Give the complete IUPAC name for each of the...Ch. 21 - Give the complete IUPAC name for each of the...Ch. 21 - Butane is used as a fuel in disposable lighters....Ch. 21 - Write Lewis structures and name the five...Ch. 21 - Write Lewis structures for the Cis -trans isomers...Ch. 21 - Write structures for the three isomers of the...Ch. 21 - Isooctane is the common name of the isomer of...Ch. 21 - Write Lewis structures and IUPAC names for the...Ch. 21 - Write Lewis structures and IUPAC names for all...Ch. 21 - Name and write the structures of all isomers of...Ch. 21 - Write the structures for all the isomers of the...Ch. 21 - Write Lewis structures and describe the molecular...Ch. 21 - Benzene is one of the compounds used as an octane...Ch. 21 - Teflon is prepared by the polymerization of...Ch. 21 - Write two complete, balanced equations for each of...Ch. 21 - Write two complete, balanced equations for each of...Ch. 21 - What mass of 2-bromopropane could be prepared from...Ch. 21 - Acetylene is a very weak acid; however, it will...Ch. 21 - Ethylene can be produced by the pyrolysis of...Ch. 21 - Why do the compounds hexane, hexanol, and hexane...Ch. 21 - Write condensed formulas and provide IUPAC names...Ch. 21 - Give the complete IUPAC name for each of the...Ch. 21 - Give the complete IUPAC name and the common name...Ch. 21 - Write the condensed structures of both isomers...Ch. 21 - Write the condensed structures of all isomers with...Ch. 21 - Draw the condensed formulas for each of the...Ch. 21 - MTBE, Methyl tert -butyl ether, CH3OC(CH3)3, is...Ch. 21 - Write two complete balanced equations for each of...Ch. 21 - Write two complete balanced equations for each of...Ch. 21 - Order the following molecules from least to most...Ch. 21 - Predict the products of oxidizing the molecules...Ch. 21 - Predict the products of reducing the following...Ch. 21 - Explain why it is not possible to possible a...Ch. 21 - How does hybridization of the substituted carbon...Ch. 21 - Fatty acids are carboxylic acids that have long...Ch. 21 - Write a condensed structural formula, such as...Ch. 21 - Write a condensed structural formula, such as...Ch. 21 - The foul odor of rancid butter is caused by...Ch. 21 - Write the two-resonance structures for the acetate...Ch. 21 - Write two complete, balanced equations for each of...Ch. 21 - Write two complete balanced equations for each of...Ch. 21 - Yields in organic reactions are sometimes low....Ch. 21 - Alcohols A, B and C all have the composition C4H...Ch. 21 - Write the Lewis structures of both isomers with...Ch. 21 - What is the molecular structure about the nitrogen...Ch. 21 - Write the two resonance structures for the...Ch. 21 - Draw Lewis structures for pyridine and its...Ch. 21 - Write the Lewis structures of all isomers with the...Ch. 21 - Write two complete balanced equations for the...Ch. 21 - Write two complete, balanced equations for each of...Ch. 21 - Identify any carbon atoms that change...Ch. 21 - Identify any carbon atoms that change...Ch. 21 - Identify any carbon atoms that change...
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- The ester with the formula C8H16O2 gives an alcohol and an acid when hydrolyzed. When the alcohol is isolated and oxidized, it forms a ketone. Which of these formulas cannot be the ester?arrow_forwardDraw the condensed structural formula for a carboxylic acid that has the formula C6H12O2, with no substituents.arrow_forward. (a) The insecticide methoprene (see Fig. 7.32d) is an ester. Write the structural formulas for the alcohol and the carboxylic acid that react to form it. Name the alcohol.(b) Suppose that the carboxylic acid from part (a) is changed chemically so that the OCH3 group is replaced by a hydrogen atom and the COOH group is replaced by a CH3 group. Name the hydrocarbon that would result.arrow_forward
- The IUPAC name for a carboxylic acid is based on thename of the hydrocarbon with the same number of carbonatoms. The ending -oic is appended, as in ethanoic acid,which is the IUPAC name for acetic acid. Draw the structureof the following acids: (a) methanoic acid, (b) pentanoicacid, (c) 2-chloro-3-methyldecanoic acid.arrow_forwardWrite the chemical equation for the reaction of propanoic acid with 1-butanol (an alcohol). The formula of 1-butanol is CH-CH-CH2-CH2-OH. Which is formula of the this rule of reaction?arrow_forwarddraw the structure of all monobromo derivatives of pentane, C5H11Br, which contain a 4 carbon chainarrow_forward
- Write two complete, balanced equations for each of the following reactions, one using condensed formulas and one using Lewis structures:(a) ethanol reacts with propionic acid(b) benzoic acid, C6H5CO2H, is added to a solution of sodium hydroxidearrow_forwardIn an esterification reaction, a carboxylic acid reacts with an excess of alcohol in acidic conditions to form an ester. Draw the structure of the ester product in the reaction between pentanoic acid and 1‑propanol.arrow_forwardWhen the conjugate acid of aniline, C6H5NH3+, reacts with the acetate ion, the following reaction takes place: C6H5NH3+(aq)+CH3COO(aq)C6H5NH2(aq)+CH3COOH(aq) If Kafor C6H5NH3+ is 1.35105 and Kafor CH3COOH is 1.86105 , what is K for the reaction?arrow_forward
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