Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Textbook Question
Chapter 21, Problem 90CWP
Which of the following molecules exhibit(s) optical isomerism?
a. cis-Pt(NH3)2Cl2
b. trans-Ni(en)2Br2 (en is ethylenediamine)
c. cis-Ni(en)2Br2 (en is ethylenediamine)
d.
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Chapter 21 Solutions
Chemistry
Ch. 21 - What two first-row transition metals have...Ch. 21 - Prob. 2RQCh. 21 - Prob. 3RQCh. 21 - Prob. 4RQCh. 21 - Prob. 5RQCh. 21 - Prob. 6RQCh. 21 - Prob. 7RQCh. 21 - Prob. 8RQCh. 21 - Prob. 9RQCh. 21 - Prob. 10RQ
Ch. 21 - Prob. 1ALQCh. 21 - Prob. 2ALQCh. 21 - Prob. 3ALQCh. 21 - Prob. 4ALQCh. 21 - Prob. 5QCh. 21 - Four different octahedral chromium coordination...Ch. 21 - Prob. 7QCh. 21 - Prob. 8QCh. 21 - Prob. 9QCh. 21 - Prob. 10QCh. 21 - Prob. 11QCh. 21 - Prob. 13QCh. 21 - Prob. 14QCh. 21 - Which of the following ligands are capable of...Ch. 21 - Prob. 16QCh. 21 - Prob. 17QCh. 21 - What is the maximum number of unpaired d electrons...Ch. 21 - Prob. 19QCh. 21 - Prob. 20QCh. 21 - Prob. 21QCh. 21 - Prob. 22QCh. 21 - Prob. 23ECh. 21 - Prob. 24ECh. 21 - Prob. 25ECh. 21 - Prob. 26ECh. 21 - Prob. 27ECh. 21 - Prob. 28ECh. 21 - Prob. 29ECh. 21 - Prob. 30ECh. 21 - Prob. 31ECh. 21 - When an aqueous solution of KCN is added to a...Ch. 21 - Consider aqueous solutions of the following...Ch. 21 - A coordination compound of cobalt(III) contains...Ch. 21 - Prob. 35ECh. 21 - Prob. 36ECh. 21 - Prob. 37ECh. 21 - Prob. 38ECh. 21 - Prob. 39ECh. 21 - Give formulas for the following complex ions. a....Ch. 21 - Prob. 41ECh. 21 - Prob. 42ECh. 21 - Prob. 43ECh. 21 - Amino acids can act as ligands toward transition...Ch. 21 - Prob. 45ECh. 21 - Prob. 46ECh. 21 - Prob. 47ECh. 21 - Prob. 48ECh. 21 - Prob. 49ECh. 21 - Prob. 50ECh. 21 - Prob. 51ECh. 21 - Prob. 52ECh. 21 - Prob. 53ECh. 21 - Prob. 54ECh. 21 - The CrF64 ion is known to have four unpaired...Ch. 21 - Prob. 56ECh. 21 - Prob. 57ECh. 21 - The complex ion Fe(CN)63 is paramagnetic with one...Ch. 21 - Prob. 59ECh. 21 - Prob. 60ECh. 21 - Prob. 61ECh. 21 - Prob. 62ECh. 21 - The wavelength of absorbed electromagnetic...Ch. 21 - The complex ion NiCL42 has two unpaired electrons,...Ch. 21 - How many unpaired electrons are present in the...Ch. 21 - The complex ion PdCl42is diamagnetic. Propose a...Ch. 21 - Prob. 67ECh. 21 - Prob. 68ECh. 21 - Prob. 69ECh. 21 - Prob. 70ECh. 21 - Silver is sometimes found in nature as large...Ch. 21 - Prob. 72ECh. 21 - Prob. 73AECh. 21 - Prob. 74AECh. 21 - Prob. 75AECh. 21 - The compound cisplatin, Pt(NH3)2Cl2, has been...Ch. 21 - Prob. 77AECh. 21 - Prob. 78AECh. 21 - Prob. 79AECh. 21 - Prob. 80AECh. 21 - Prob. 81AECh. 21 - Name the following coordination compounds. a....Ch. 21 - Prob. 83AECh. 21 - Prob. 84AECh. 21 - Prob. 85AECh. 21 - Prob. 86AECh. 21 - Carbon monoxide is toxic because it binds more...Ch. 21 - Prob. 88AECh. 21 - Prob. 89CWPCh. 21 - Which of the following molecules exhibit(s)...Ch. 21 - Prob. 91CWPCh. 21 - The following table indicates the number of...Ch. 21 - Prob. 93CWPCh. 21 - Which of the following statement(s) is( are) true?...Ch. 21 - Consider the following complex ion, where A and B...Ch. 21 - Consider the pseudo-octahedral complex ion of...Ch. 21 - Prob. 97CPCh. 21 - Prob. 98CPCh. 21 - Chelating ligands often form more stable complex...Ch. 21 - Prob. 100CPCh. 21 - Prob. 101CPCh. 21 - Prob. 102CPCh. 21 - Sketch and explain the most likely crystal field...Ch. 21 - Ethylenediaminetetraacetate (EDTA4 ) is used as a...Ch. 21 - Prob. 105CPCh. 21 - The ferrate ion, FeO42, is such a powerful...Ch. 21 - Ammonia and potassium iodide solutions are added...Ch. 21 - a. In the absorption spectrum of the complex ion...Ch. 21 - There are three salts that contain complex ions of...
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- Chelating ligands often form more stable complex ions than the corresponding monodentate ligands with the same donor atoms. For example, Ni2+(aq)+6NH3(aq)Ni(NH3)62+(aq)K=3.2108Ni2+(aq)+3en(aq)Ni(en)32+(aq)K=1.61018Ni2+(aq)+penten(aq)Ni(penten)2+(aq)K=2.01019 where en is ethylenediamine and penten is This increased stability is called the chelate effect. Based on bond energies, would you expect the enthalpy changes for the above reactions to be very different? What is the order (from least favorable to most favorable) of the entropy changes for the above reactions? How do the values of the formation constants correlate with S? How can this be used to explain the chelate effect?arrow_forwardChemistry is the most predominant complex [Ni(en)3 ]2+ , [Ni(OH2 )2(en)2 ]2+ , or [Ni(OH2 )4 (en)]2+ ? and whyarrow_forwardWhy dp transition elements show variable oxidation states? In 3d series (Sc to Zn), which element shows the maximum number of oxidation states and why?arrow_forward
- 1) Consider the transition metal M which, in neutral form, has an electronic configuration ending in (n-1)d5 ns1. M forms the following complexes: [MCl6]K3, [M(CN)6]K4 and [M(en)3]Cl3. 1a) Fill in the following table Complex ion Oxidation state of M CN Electronic configuration outer shell of M [MCl6]K3 [M(CN)6]K4 [M(en)3]Cl3arrow_forwardCoordination Chemistry. [Pt(py)(NH3)(NO2)Cl] has three possible isomers: A, B, C. Show how these isomers will be synthesized.arrow_forward
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