ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
6th Edition
ISBN: 9781266633973
Author: SMITH
Publisher: MCG
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Chapter 22, Problem 41P
Interpretation Introduction

(a)

Interpretation: The starting materials that are needed to synthesize the given compound by a crossed Claisen reaction are to be shown.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-ketoester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(b)

Interpretation: The starting materials that are needed to synthesize the given compound by a crossed Claisen reaction are to be shown.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-ketoester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(c)

Interpretation: The starting materials that are needed to synthesize the given compound by a crossed Claisen reaction are to be shown.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-ketoester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(d)

Interpretation: The starting materials that are needed to synthesize the given compound by a crossed Claisen reaction are to be shown.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-ketoester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

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Chapter 22 Solutions

ORGANIC CHEMISTRY

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