Concept explainers
(a)
Interpretation: To determine the oxidation number of the metals in given compounds.
Concept Introduction:
Oxidation number:
The number of electrons losses or gained form or to an atom is known as Oxidation number and it is varied in while the atom involving in
(b)
Interpretation: To determine the oxidation number of the metals in given compounds.
Concept Introduction:
Oxidation number:
The number of electrons losses or gained form or to an atom is known as Oxidation number and it is varied in while the atom involving in redox reaction.
(c)
Interpretation: To determine the oxidation number of the metals in given compounds.
Concept Introduction:
Oxidation number:
The number of electrons losses or gained form or to an atom is known as Oxidation number and it is varied in while the atom involving in redox reaction.
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Chapter 22 Solutions
CHEMISTRY:ATOMS FIRST (LL)>CUSTOM PKG.<
- Four different octahedral chromium coordination compounds exist that all have the same oxidation state for chromium and have H2O and Cl as the ligands and counterions. When 1 mole of each of the four compounds is dissolved in water, how many moles of silver chloride will precipitate upon addition of excess AgNO3?arrow_forwardPlatinum(II) forms many complexes, among them those with the following ligands. Give the formula and charge of each complex. (a) two ammonia molecules and one oxalate ion (C2O42-) (b) two ammonia molecules, one thiocyanate ion (SCN-), and one bromide ion (c) one ethylenediamine molecule and two nitrite ionsarrow_forwardWhich is more acidic and why? [Fe(H2O)6]2+ or [Fe(NH3)(H2O)5]2+arrow_forward
- Determine the oxidation state of the coordinated metal atom in each of the following compounds:(a) K[Co(NH3)2(CN)4]; (b) Os(CO)5; (c) Na[Co(OH2)3(OH)3].arrow_forwardWhat type of isomerism is shown by [CO(NH3)5ONO]Cl2? (ii) On the basis of crystal field theory, write the electronic configuration for d4 ion if A0 < P. (iii) Write the hybridization and shape of [Fe(CN)6]3-. (Atomic number of Fe — 26)arrow_forwardDraw orbital-energy splitting diagrams and use the spectro-chemical series to show the orbital occupancy for each of the fol-lowing (assuming that H₂O is a weak-field ligand):(a) [Cr(CN)₆]³⁻(b) [Rh(CO)₆]³⁺(c) [Co(OH)₆]⁴⁻arrow_forward
- Mention the types of structural isomerism present in metal complexes and indicate to which of them the following compound pair belongs: [Co(NH3)6][Cr(CN)6] and [Cr(NH3)6][Co(CN)6].arrow_forwardName each of the compounds or ions given, including the oxidation state of the metal. (a) [Co(CO3)3]3− (note that CO32− is bidentate in this complex)(b) [Cu(NH3)4]2+(c) [Co(NH3)4Br2]2(SO4)3(d) [Pt(NH3)4][PtCl4](e) [Cr(en)3](NO3)3(f) [Pd(NH3)2Br2] (square planar)(g) K3[Cu(Cl)5](h) [Zn(NH3)2Cl2]arrow_forwardMention and draw the types of structural isomerism present in metal complexes and indicate to which of them the following compound pair belongs: [Co(NH3)6][Cr(CN)6] and [Cr(NH3)6][Co(CN)6].arrow_forward
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