(a) Interpretation: The alkyl halide needed to prepare carboxylic acid by the malonic ester synthesis is to be predicted. Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO 2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

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Answer 1

Question

Chapter 23, Problem 23.23P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare carboxylic acid by the malonic ester synthesis is to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Interpretation Introduction

(b)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Interpretation Introduction

(c)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

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Answer 2

Question

Chapter 23, Problem 23.23P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare carboxylic acid by the malonic ester synthesis is to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Interpretation Introduction

(b)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Interpretation Introduction

(c)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

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Answer 3

Question

Chapter 23, Problem 23.23P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare carboxylic acid by the malonic ester synthesis is to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Interpretation Introduction

(b)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Interpretation Introduction

(c)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

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Answer 4

Question

Chapter 23, Problem 23.23P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare carboxylic acid by the malonic ester synthesis is to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Interpretation Introduction

(b)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Interpretation Introduction

(c)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

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Answer 5

Chapter 23, Problem 23.23P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare carboxylic acid by the malonic ester synthesis is to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Interpretation Introduction

(b)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Interpretation Introduction

(c)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Answer 6

Chapter 23, Problem 23.23P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare carboxylic acid by the malonic ester synthesis is to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Answer 7

Chapter 23, Problem 23.23P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare carboxylic acid by the malonic ester synthesis is to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Answer 8

Interpretation Introduction

(b)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Answer 9

Interpretation Introduction

(b)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Answer 10

Interpretation Introduction

(c)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Answer 11

Interpretation Introduction

(c)

Interpretation: The alkyl halides needed to prepare carboxylic acid by the malonic ester syntheses are to be predicted.

Concept introduction: The α hydrogen attached to the diester is acidic in nature and on heating diester followed by hydrolysis gives β- diacid which loses CO2 to give carboxylic acid. The formed acid has components of both alkyl halide and malonic ester.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 23 - Problem 23.1 Draw the enol or keto tautomer(s) of...Ch. 23 - Prob. 23.2P Ch. 23 - Problem 23.3 When phenylacetaldehyde is dissolved...Ch. 23 - Prob. 23.4P Ch. 23 - Problem 23.5 Which bonds in the following...Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - Prob. 23.8P Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

Solution Summary: The author explains that the alkyl halide needed to prepare carboxylic acid by the malonic ester synthesis is to be predicted.

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Chapter 23 Solutions