(a) Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined. Concept introduction: Gabriel synthesis is a method of preparation of primary amines . This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

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Answer 1

Question

Chapter 23.6, Problem 7P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

Interpretation Introduction

(b)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

Interpretation Introduction

(c)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

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Answer 2

Question

Chapter 23.6, Problem 7P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

Interpretation Introduction

(b)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

Interpretation Introduction

(c)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

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Answer 3

Question

Chapter 23.6, Problem 7P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

Interpretation Introduction

(b)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

Interpretation Introduction

(c)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

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Answer 4

Question

Chapter 23.6, Problem 7P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

Interpretation Introduction

(b)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

Interpretation Introduction

(c)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

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Answer 5

Chapter 23.6, Problem 7P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

Interpretation Introduction

(b)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

Interpretation Introduction

(c)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

Answer 6

Chapter 23.6, Problem 7P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

Answer 7

Chapter 23.6, Problem 7P

Interpretation Introduction

(a)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

Answer 8

Interpretation Introduction

(b)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

Answer 9

Interpretation Introduction

(b)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

Answer 10

Interpretation Introduction

(c)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

Answer 11

Interpretation Introduction

(c)

Interpretation: The alkyl halide needed to prepare the given primary amine by Gabriel synthesis is to be determined.

Concept introduction: Gabriel synthesis is a method of preparation of primary amines. This is a nucleophilic substitution reaction. The phthalimide in presence of base forms the resonance stabilized anion which acts as a nucleophile and attacks the electrophilic carbon of alkyl haides.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 23.2 - Prob. 1P Ch. 23.3 - Prob. 2P Ch. 23.3 - Prob. 3P Ch. 23.4 - Prob. 4P Ch. 23.6 - Prob. 7P Ch. 23.6 - Prob. 8P Ch. 23.6 - Prob. 9P Ch. 23.6 - Prob. 10P Ch. 23.6 - Prob. 11P Ch. 23.6 - Prob. 12P

Solution Summary: The author explains how the alkyl halide needed to prepare the given primary amine by Gabriel synthesis is heptyl bromide.

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Chapter 23 Solutions