(a) Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using − OH , H 2 O is to be drawn. Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry . In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β -hydroxyaldehyde or β -hydroxyketone which on further dehydration gives the conjugated enone.

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Answer 1

Question

Chapter 24, Problem 24.30P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

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Draw the aldol product formed from each compound.

Draw the aldol product formed from each pair of starting materials using −OH, H2O.

A key step in the synthesis of donepezil is a directed aldol reaction that forms α,β- unsaturated carbonyl compound X. What carbonyl starting materials are needed to prepare X using a directed aldol reaction? What reagents are needed to convert X to donepezil?

Answer 2

Question

Chapter 24, Problem 24.30P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

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Answer 3

Question

Chapter 24, Problem 24.30P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Expert Solution & Answer

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Answer 4

Question

Chapter 24, Problem 24.30P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Expert Solution & Answer

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Answer 5

Chapter 24, Problem 24.30P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 6

Chapter 24, Problem 24.30P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 7

Chapter 24, Problem 24.30P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 8

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 9

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 10

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 11

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 24 - Prob. 24.1P Ch. 24 - Prob. 24.2P Ch. 24 - Problem 24.3 What unsaturated carbonyl compound is...Ch. 24 - Prob. 24.4P Ch. 24 - Prob. 24.5P Ch. 24 - Prob. 24.6P Ch. 24 - Problem 24.7 Draw the products formed in each...Ch. 24 - Problem 24.8 Draw the products formed in the...Ch. 24 - Prob. 24.9P Ch. 24 - Prob. 24.10P

Solution Summary: The author explains that aldol reaction is the condensation reaction of the organic chemistry.

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Chapter 24 Solutions