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Concept explainers
(a)
Interpretation:
Difference between coordination number and oxidation number is to be defined.
Concept introduction:
When all the ligands and shared paired electron are removed from a coordination compound, the number of charge on central metal is called oxidation number. And a number of ligands are known as co-ordination number.
(b)
Interpretation:
Difference between monodentate and polydentate is to be defined.
Concept introduction:
During metal-ligand complex formation different ligands bind to the central metal ion which is known as coordination compound. Ligands can be of two types monodentate and polydentate.
(c)
Interpretation:
Difference between cis and trans isomers is to be defined.
Concept introduction:
The phenomenon of isomers having different structural composition is known as Structural isomerism. Isomers can be present in different forms known as Cis and Trans-forms.
(d)
Interpretation:
Difference Dextro and Levo rotatory are to be defined.
Concept introduction:
The phenomenon of isomers having different structural composition is known as Structural isomerism. And the isomers can rotate the plane-polarized light and can be divided into Dextro and Levo rotatory.
(e)
Interpretation:
Difference between low spin and high spin complex is to be defined.
Concept introduction:
According to crystal field theory splitting of d orbital occurs which leads to energy emission in the form of light. Here crystal field splitting is presented as
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Chapter 24 Solutions
EBK GENERAL CHEMISTRY
- What is the coordination number of the central metal atom in the following complexes? (a) [Fe(H2O)63+] (b) [Pt(NH3)Br3] (c) [V(en)Cl42] (d) [Au(CN)2+]arrow_forwardFour different octahedral chromium coordination compounds exist that all have the same oxidation state for chromium and have H2O and Cl as the ligands and counterions. When 1 mole of each of the four compounds is dissolved in water, how many moles of silver chloride will precipitate upon addition of excess AgNO3?arrow_forwardClassify each ligand as monodentate, bidentate, and so on. (a) (CH3)3P (b) H2N(CH2)2NH(CH2)2NH2 (c) H2Oarrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningPrinciples of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage LearningChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
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