EBK ORGANIC CHEMISTRY AS A SECOND LANGU
4th Edition
ISBN: 9781119234722
Author: Klein
Publisher: JOHN WILEY+SONS,INC.-CONSIGNMENT
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Chapter 2.5, Problem 2.13P
For each IR spectrum below, identify whether it is consistent with the structure of an alcohol, a
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5. Place the letter of the spectrum next to the name of the compound that it represents.
Compound
Letter
Acetone
1,2-dichloroethane
1,1,2-trichloroethane
2,2-dimethoxypropane
1-bromopropane
2-bromopropane
What are the major IR absorptions in the functional group region for each compound?
Please solve this organic chemistry question
A carboxylic acid with the molecular formula C5H10O2 is treated with thionyl chloride to give compound A. Compound A has only one signal in its 1H NMR spectrum. Please figure out this carboxylic acid. You can write out name directly or molecular formula with functional groups (e.g. isopropanol (CH3)3COH). Hint: Only one H NMR signal means all hydrogens are in the same chemical status.
Chapter 2 Solutions
EBK ORGANIC CHEMISTRY AS A SECOND LANGU
Ch. 2.3 - For each of the following compounds, determine...Ch. 2.3 - For each of the following compounds, determine...Ch. 2.3 - For each of the following compounds, determine...Ch. 2.3 - For each of the following compounds, determine...Ch. 2.3 - The following compound has three carbonyl groups....Ch. 2.4 - Predict which of the following C=C bonds will...Ch. 2.4 - The C=C bond in the following compound produces an...Ch. 2.5 - For each IR spectrum below, identify whether it is...Ch. 2.5 - For each IR spectrum below, identify whether it is...Ch. 2.5 - For each IR spectrum below, identify whether it is...
Ch. 2.5 - For each IR spectrum below, identify whether it is...Ch. 2.5 - For each IR spectrum below, identify whether it is...Ch. 2.5 - For each IR spectrum below, determine whether it...Ch. 2.5 - For each IR spectrum below, determine whether it...Ch. 2.5 - For each IR spectrum below, determine whether it...Ch. 2.5 - For each IR spectrum below, determine whether it...Ch. 2.5 - For each IR spectrum below, determine whether it...Ch. 2.5 - For each IR spectrum below, determine whether it...Ch. 2.5 - For each IR spectrum below, determine whether it...Ch. 2.6 - Prob. 2.22P
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- What is this compound base on the IR spectrum?arrow_forwardQ-2. Look at the following "C-NMR spectrum (Lower) and two DEPT spectra (C,H,CI): 131 ppm 140 130 120 110 100 90 80 70 60 s0 40 30 20 10 ppm Label all the signals as CH,, CH,. CH or C. Put you labels in the lower spectrum. i) ii) Draw one possible structure for the compound.arrow_forward3. a) Draw the below structure and answer the following questions. CI CH2COCH2CH3 i. Identify the chemically equivalent protons in the structure. Explain your answer. ii. Mention how many peaks you would expect in the HNMR spectrum of the compound. Explain the position of each peak in the spectrum. iii. Mention what would be the splitting pattern of each peak with proper explanation. iv. Draw the HNMR spectrum of the compound. b) Explain why the delta/ ppm scale was introduced instead of Hz in NMR analysis with example.arrow_forward
- True or False 1. A molecule that is "IR inactive" means that it does not produce any signal due to no vibration. 2. Infrared spectroscopic data is reported in wavenumber (cm-1) against absorbance because they have a linear relationship. 3. The signals observed from a molecule of chloropropane will have a higher wavenumber than iodopropane. 4. The signals observed from the C-C bond in an alkene will report at a higher wavenumber than the C-C bond in an alkyne.arrow_forwardBelow are three MS spectra, Spectra 1, 2, and 3. Each of this mass spectrum corresponds to either Compound A (contains one Cl in the molecular formula), Compound B (one I in the molecular formula), and Compound C (one Br in the molecular formula). Identify which spectra corresponds to which compound. Provide explanations for your choices.arrow_forwardWhich one of the pi bonds in the molecules shown below will produce a stronger signal in an IR spectrum? Yes, compound I produces a stronger signal because it has a larger dipole moment. O Yes, compound II produces a stronger signal because it has a larger dipole moment. No, the alkene groups produce similar signals because they have similar double bonds. O No, the alkene groups produce similar signals because they both contain a similar number of atoms.arrow_forward
- The DEPT-90 spectrum exhibits 6 in the 0-50 ppm region The DEPT-135 spectrum exhibits x 100 ppm region that is a positive ▾ C6 signal(s) for the CH groups: ▼ 1,2,6 ✓ in the sp2 hybridized region 100-150 C3 and C4 ▼ signal(s) (only the quaternary carbon atoms, signal(s), indicating the presence of a methylene group (CH₂) attached to an oxygen atom, are missing); there is C5 ▼ C1 and C2 ▼ and signal(s) in the 50-arrow_forwardUsing the Molecular Ion to Identify a Compound Pent-1-ene and pent-1-yne are low-boiling hydrocarbons that have different molecular ions in their mass spectra. Match each hydrocarbon to its mass spectrum.arrow_forwardEach of the following IR spectra (shown in the picture, a-f) corresponds to one of the five isomers of C4H80. Match the spectrum to the correct structure and stated the reason.arrow_forward
- Identify the functional group of the molecule in the following IR spectrum.arrow_forwardAcetyleugenol: Match the peaks to the appropriate number on the structure. A letter may correspond to more than one number. 10 11 2. 2 3. 3 44 5. 5 6. 6arrow_forward1,3-Dibromobutane has the 1H NMR spectrum shown below. Map each hydrogen atom in the molecule of 1,3-dibromobutane with its corresponding peak number.arrow_forward
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