Principles of Instrumental Analysis, 6th Edition
6th Edition
ISBN: 9788131525579
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cenage Learning
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Question
Chapter 25, Problem 25.11QAP
Interpretation Introduction
Interpretation:
Scan rate at experiment 2 should be calculated.
Concept introduction:
The peak current can be represented as follows:
Here,
Ip = peak current
n = number of electrons transferred in the redox event
A = electrode surface area
C = concentration
D = diffusion coefficient
V = scan rate
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Students have asked these similar questions
An analyst wants to find out the active surface of his electrode before conducting his analyzes. To do this, he carried out a series of measurements by cyclic voltammetry (CV) using a 1 mM solution of K4Fe(CN)6 dissolved in 0.1M NaCl. He recorded the anodic peak intensity (ip) corresponding to the oxidation of Fe(II) to Fe(III) as a function of the scanning speed (v) of the CV (see table). What is the active surface of the electrode?
Data: Fe diffusion coefficient (CN)64-, D = 6.67x10-6 cm2/s
Randles-Sevcik equation ip = (2,69x105)n3/2ACD1/2v1/2
rate (v/s)
ip (A)
5,00E-02
5,75E-05
1,00E-01
7,68E-05
2,00E-01
9,94E-05
5,00E-01
1,42E-04
1,00E+00
2,07E-04
[3] The following Figure is the electrocapillary curves (A) and differential capacitance curves (B) for mercury in contact
with 0.5 M Na,SO4 in the presence and absence of n-heptanol .
440-
(A)
(B)
420
Na,So.
400
Na, So,
CHOH
360
Na so,
20
340-
Na So,
CH,OH
10
320
0.4
0.8
12
1.6
20
24
0.4
0.8
1.2
-EV ex NCE)
1.6
2.0
-EV e NCE
(a) How do the curves in figure (A) relate to those in figure (B)?
(b) What implications can be derived from the flat region in the electrocapillary curves in the presence of n-heptyl alcohol?
(c) If we measure the electrocapillary curve of mercury in contact with 0.5 M Na,SO4 at higher temperature, what changes
in the curve can be observed? Try to give explanation of these changes.
How long will it take to dissolve 2 mg of metal A (atomic weight 100) in a solution
containing A2+ from a metal electrode with area of 1.5 cm2 at an overpotential of
= 0.2 V? The exchange current density (j0) for A is 3x10-3 A/cm2, the temperature
T=298 K and the symmetry factor =0.4.
Chapter 25 Solutions
Principles of Instrumental Analysis, 6th Edition
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