Concept explainers
(a)
Interpretation: The organic product that is formed in the given reaction is to be determined.
Concept introduction: The various organic reactions form different organic products with the help of the variety of reagents. Some of the organic compounds are formed by the characteristic action of the various functional groups present in them.
Answer to Problem 25.65P
The product of the given reaction is,
Explanation of Solution
The product formed by the reaction of the given
Figure 1
In the given reaction, nitrogen present in ammonia acts as a nucleophile and attacks at carbon atom which is directly attached with electronegative chlorine atom. Chlorine ion being a good leaving group, leaves the reactant site simultaneously which results in the formation of a desired
The product of the given reaction is shown in Figure 1.
(b)
Interpretation: The organic product that is formed in the given reaction is to be determined.
Concept introduction: The various organic reactions form different organic products with the help of the variety of reagents. Some of the organic compounds are formed by the characteristic action of the various functional groups present in them.
Answer to Problem 25.65P
The product of the given reaction is
Explanation of Solution
The product formed by the reaction of the given reactant with
Figure 2
In the given reaction, nitrogen present in the given reaction is firstly reacts with
The product of the given reaction is
(c)
Interpretation: The organic product that is formed in the given reaction is to be determined.
Concept introduction: The various organic reactions form different organic products with the help of the variety of reagents. Some of the organic compounds are formed by the characteristic action of the various functional groups present in them.
Answer to Problem 25.65P
The product of the given reaction is,
Explanation of Solution
The product formed by the reaction of given nitro compound with tin in the presence of an acid is shown as,
Figure 3
In the given reaction, nitro group of the reactant reacts with
The product of the given reaction is shown in Figure 3.
(d)
Interpretation: The organic product that is formed in the given reaction is to be determined.
Concept introduction: The various organic reactions form different organic products with the help of the variety of reagents. Some of the organic compounds are formed by the characteristic action of the various functional groups present in them.
Answer to Problem 25.65P
The product of the given reaction is,
Explanation of Solution
The product formed by the reaction of given cyano compound with
Figure 4
In the given reaction, cyano group of the reactant reacts with lithium aluminum hydride that results in the reduction of cyano group into an amino group in the presence of water. Thus, lithium aluminum hydride being a strong reducing agent forms a desired amine product.
The product of the given reaction is shown in Figure 4.
(e)
Interpretation: The organic product that is formed in the given reaction is to be determined.
Concept introduction: The various organic reactions form different organic products with the help of the variety of reagents. Some of the organic compounds are formed by the characteristic action of the various functional groups present in them.
Answer to Problem 25.65P
The product of the given reaction is,
Explanation of Solution
The product formed by the reaction of given amide compound with
Figure 5
In the given reaction, amide group of the reactant reacts with lithium aluminum hydride that results in the reduction of amide group into an amino group in the presence of water. Thus, lithium aluminum hydride being a strong reducing agent forms a desired amine product.
The product of the given reaction is shown in Figure 5.
(f)
Interpretation: The organic product that is formed in the given reaction is to be determined.
Concept introduction: The various organic reactions form different organic products with the help of the variety of reagents. Some of the organic compounds are formed by the characteristic action of the various functional groups present in them.
Answer to Problem 25.65P
The product of the given reaction is,
Explanation of Solution
The product formed by the reaction of given amine compound with an anhydride is shown as,
Figure 6
In the given reaction, amine group of the reactant reacts with the anhydride to form a desired amide product. This amide product is a secondary amide.
The product of the given reaction is shown in Figure 6.
(g)
Interpretation: The organic product that is formed in the given reaction is to be determined.
Concept introduction: The various organic reactions form different organic products with the help of the variety of reagents. Some of the organic compounds are formed by the characteristic action of the various functional groups present in them.
Answer to Problem 25.65P
The product of the given reaction is,
Explanation of Solution
The product formed by the reaction of given cyclic secondary amine with sodium nitrite in the presence of an acid is shown as,
Figure 7
In the given reaction, amine group of the reactant reacts with
The product of the given reaction is shown in Figure 7.
(h)
Interpretation: The organic product that is formed in the given reaction is to be determined.
Concept introduction: The various organic reactions form different organic products with the help of the variety of reagents. Some of the organic compounds are formed by the characteristic action of the various functional groups present in them.
Answer to Problem 25.65P
The product of the given reaction is,
Explanation of Solution
The product formed by the reaction of given cyclic secondary amine with an
Figure 8
In the given reaction, amine group of the reactant reacts with benzaldehyde in the presence of
The product of the given reaction is shown in Figure 8.
(i)
Interpretation: The organic product that is formed in the given reaction is to be determined.
Concept introduction: The various organic reactions form different organic products with the help of the variety of reagents. Some of the organic compounds are formed by the characteristic action of the various functional groups present in them.
Answer to Problem 25.65P
The product of the given reaction is,
Explanation of Solution
The product formed by the reaction of given cyclic amine compound with an cyclic
Figure 9
In the given reaction, amine group of the reactant reacts with a cyclic ketonic compound to form a desired product.
The product of the given reaction is shown in Figure 9.
(j)
Interpretation: The organic product that is formed in the given reaction is to be determined.
Concept introduction: The various organic reactions form different organic products with the help of the variety of reagents. Some of the organic compounds are formed by the characteristic action of the various functional groups present in them.
Answer to Problem 25.65P
The product of the given reaction is
Explanation of Solution
The product formed by the reaction of given secondary amine compound with methyl iodide in the presence of
Figure 10
In the given reaction, amine group of the reactant reacts with
The product of the given reaction is
Want to see more full solutions like this?
Chapter 25 Solutions
Organic Chemistry (Looseleaf)
- Fill in the missing reagents a-e in the following scheme:arrow_forwardAs we have seen in this chapter, carbon-carbon double bonds are electron-rich regions that are attacked by electrophiles (e.g., HBr); they are not attacked by nucleophiles (e.g., diethylamine). However, when the carbon-carbon double bond has a carbonyl group adjacent to it, the double bond reacts readily with nucleophiles by nucleophilic addition (Section 19.8). Account for the fact that nucleophiles add to a carbon-carbon double bond adjacent to a carbonyl group and account for the regiochemistry of the reaction.arrow_forwardChoose the appropriate reagent for the following reaction. A) TsCl/pyridine B) SOCl2/pyridine C) ZnCl2 D) PBr3 E) HIarrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage LearningOrganic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning